Self-assembly of a trigonal bipyramidal architecture with stabilisation of iron in three spin states

2021 ◽  
Author(s):  
Lauren L. K. Taylor ◽  
Iñigo J. Vitorica-Yrezabal ◽  
Ivana Borilović ◽  
Floriana Tuna ◽  
Imogen A. Riddell
Keyword(s):  
Oxidation State ◽  
High Spin ◽  
Self Assembly ◽  
Metal Salt ◽  
Spin States ◽  
Trigonal Bipyramidal ◽  
Mixed Oxidation ◽  
High Spin Iron

Self-assembly of a trigonal bipyramidal architecture with a central mixed oxidation state star from a heterotopic ligand and a single metal salt. Characterisation confirms incorporation of iron as low-spin iron(ii), high-spin iron(ii) and iron(iii).

scholarly journals Spin states, bonding and magnetism in mixed valence iron(0)–iron(II) complexes

2021 ◽  
Author(s):  
Daniel Kim ◽  
Daniel Wilson ◽  
Majed Fataftah ◽  
Brandon Mercado ◽  
Patrick Holland
Keyword(s):  
High Spin ◽  
Computational Analysis ◽  
Mixed Valence ◽  
Lewis Base ◽  
Zero Field ◽  
Spin States ◽  
Iron Site ◽  
Zero Field Splitting ◽  
Structure Description ◽  
High Spin Iron

We report the synthesis of two complexes featuring unsupported Fe–Fe bonds between a diketiminate/dialdiminate-coordinated iron site and a cyclopentadienyl dicarbonyl iron site. Mössbauer spectroscopy, SQUID magnetometry and computational analysis indicate that the most accurate electronic structure description is with the Fe(CO)2Cp site as low spin iron(0), and it acts as a Lewis base toward the high spin iron(II) of the LFe fragment which is a Lewis acid. In both compounds, the three-coordinate high-spin iron(II) site has large zero-field splitting (zfs), up to D = –50 cm–1.

Observation of high-spin mixed oxidation state of cobalt in ceramic Co3TeO6

2014 ◽  
Vol 116 (21) ◽  
pp. 214106 ◽  
Author(s):  
Harishchandra Singh ◽  
Haranath Ghosh ◽  
T. V. Chandrasekhar Rao ◽  
A. K. Sinha ◽  
Parasmani Rajput
Keyword(s):  
Oxidation State ◽  
High Spin ◽  
Mixed Oxidation

DESCRIPTION OF HIGH SPIN STATES

1980 ◽  
Vol 41 (C10) ◽  
pp. C10-143-C10-154 ◽  
Author(s):  
A. Faessler
Keyword(s):  
High Spin ◽  
Spin States ◽  
High Spin States

scholarly journals Interplay between Zhang-Rice singlets and high-spin states in a model for doped NiO2 planes

2021 ◽  
Vol 103 (10) ◽  
Author(s):  
Tharathep Plienbumrung ◽  
Maria Daghofer ◽  
Andrzej M. Oleś
Keyword(s):  
High Spin ◽  
Spin States ◽  
High Spin States

High-spin states inSi28from variation after angular-momentum projection

1983 ◽  
Vol 27 (5) ◽  
pp. 2414-2416 ◽  
Author(s):  
W. Bauhoff ◽  
H. Schultheis ◽  
R. Schultheis
Keyword(s):  
Angular Momentum ◽  
High Spin ◽  
Spin States ◽  
Angular Momentum Projection ◽  
High Spin States

Negative-parity high-spin states and a possible magnetic rotation band inPr7659135

2015 ◽  
Vol 92 (5) ◽  
Author(s):  
Ritika Garg ◽  
S. Kumar ◽  
Mansi Saxena ◽  
Savi Goyal ◽  
Davinder Siwal ◽  
...  
Keyword(s):  
High Spin ◽  
Negative Parity ◽  
Magnetic Rotation ◽  
Spin States ◽  
High Spin States ◽  
Rotation Band
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