Green and Efficient Synthesis of Thioureas, Ureas, Primary O-Thiocarbamates, and Carbamates in Deep Eutectic Solvent/ Catalyst Systems Using Thiourea and Urea

2021 ◽  
Author(s):  
Nastaran Bagherzadeh ◽  
Alireza Sardarian ◽  
Iman Dindarloo

An efficient and general catalysis process was developed for the direct preparation of various primary O-thiocarbamates/carbamates as well as monosubstituted thioureas/ureas by using the thiourea/urea as biocompatible thiocarbonyl (carbonyl) sources....

RSC Advances ◽  
2015 ◽  
Vol 5 (75) ◽  
pp. 61191-61198 ◽  
Author(s):  
Najmedin Azizi ◽  
Zahra Rahimi ◽  
Masoumeh Alipour

A short and highly efficient synthesis of cyanohydrins in a recyclable and biodegradable magnetic deep eutectic solvent is described.


ChemInform ◽  
2001 ◽  
Vol 32 (15) ◽  
pp. no-no
Author(s):  
Glen Brizius ◽  
Neil Gregory Pschirer ◽  
Winfried Steffen ◽  
Katherine Stitzer ◽  
Hans-Conrad zur Loye ◽  
...  

2020 ◽  
Vol 16 (8) ◽  
pp. 1185-1190 ◽  
Author(s):  
Fatemeh Malamiri ◽  
Samad Khaksar ◽  
Rashid Badri ◽  
Elham Tahanpesar

Objective: An efficient and catalyst-free procedure for the synthesis of [1,2,4]triazolo/benzimidazolo quinazolinones has been developed in 2,2,2-trifluoroethanol or deep eutectic solvent(DESs) as a clean reaction media. Methods: All of the obtained products are known compounds and identified by IR, 1HNMR,13CNMR, and melting points. Results: Various products were obtained in good to excellent yields under reaction conditions. Conclusion: We have efficiently developed a practical and catalyst-free approach for the synthesis of [1,2,4]triazolo/benzimidazolo quinazolinones employing TFE as a clean and reusable media.


2013 ◽  
Vol 20 (1) ◽  
pp. 287-293 ◽  
Author(s):  
Balvant S. Singh ◽  
Hyacintha R. Lobo ◽  
Dipak V. Pinjari ◽  
Krishna J. Jarag ◽  
Aniruddha B. Pandit ◽  
...  

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