Rearrangements and Reductive Cleavage of 3а,6а-Diaza-1,4-diphosphapentalenes
The interaction of 1,4-dichloro-3а,6а-diaza-1,4-diphosphapentalenes with metallic Na, Li, or naphthalene-Na anion-radical salt in THF proceeds through several successive stages: dehalogenation, two types of rearrangement of the heteropentalene fragment to form...
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