scholarly journals Synthesis of diblock copolymer spheres, worms and vesicles via RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate

2021 ◽  
Author(s):  
Saul J. Hunter ◽  
Joseph R. Lovett ◽  
Oleksandr O. Mykhaylyk ◽  
Elizabeth R. Jones ◽  
Steven P. Armes
Keyword(s):  
Phase Diagram ◽  
Emulsion Polymerization ◽  
Diblock Copolymer ◽  
Aqueous Emulsion

RAFT aqueous emulsion polymerization of hydroxybutyl methacrylate using a poly(glycerol monomethacrylate) precursor leads to diblock copolymer spheres, worms or vesicles. A pseudo-phase diagram is constructed and the vesicles are briefly evaluated as a Pickering emulsifier.

scholarly journals Epoxy-Functional Sterically Stabilized Diblock Copolymer Nanoparticles via RAFT Aqueous Emulsion Polymerization: Comparison of Two Synthetic Strategies

2018 ◽  
Vol 40 (2) ◽  
pp. 1800289 ◽  
Author(s):  
Csilla György ◽  
Joseph R. Lovett ◽  
Nicholas J. W. Penfold ◽  
Steven P. Armes
Keyword(s):  
Emulsion Polymerization ◽  
Diblock Copolymer ◽  
Aqueous Emulsion

scholarly journals Synthesis of well-defined diblock copolymer nano-objects by RAFT non-aqueous emulsion polymerization of N-(2-acryloyloxy)ethyl pyrrolidone in non-polar media

2021 ◽  
Author(s):  
R. R. Gibson ◽  
A. Fernyhough ◽  
O. M. Musa ◽  
S. P. Armes
Keyword(s):  
Emulsion Polymerization ◽  
Diblock Copolymer ◽  
Aqueous Emulsion ◽  
Polar Media ◽  
Stearyl Methacrylate

RAFT non-aqueous emulsion polymerization of N-(2-acryloyloxy)ethyl pyrrolidone in n-dodecane using a poly(stearyl methacrylate) precursor is used to prepare sterically-stabilized nanoparticles, which are evaluated as a putative Pickering emulsifier.

scholarly journals Effect of lithium trifluoromethanesulfonate on the phase diagram of a liquid-crystalline amphiphilic diblock copolymer

2007 ◽  
Vol 40 (s1) ◽  
pp. s585-s589 ◽  
Author(s):  
Takeshi Yamada ◽  
Jingze Li ◽  
Chinami Koyanagi ◽  
Tomokazu Iyoda ◽  
Hirohisa Yoshida
Keyword(s):  
Phase Diagram ◽  
Diblock Copolymer ◽  
Liquid Crystalline ◽  
Amphiphilic Diblock Copolymer ◽  
Lithium Trifluoromethanesulfonate

Phase behavior of AB/CD diblock copolymer blends via coarse-grained simulation

Soft Matter ◽  
2020 ◽  
Vol 16 (12) ◽  
pp. 3069-3081
Author(s):  
Iman Ahmadian ◽  
Andrew J. Peters
Keyword(s):  
Phase Diagram ◽  
Phase Behavior ◽  
Diblock Copolymer ◽  
Coarse Grained ◽  
Copolymer Blends

A–B/C–D diblock copolymer blends with negative χBC were investigated using DPD. Novel morphologies were found and a phase diagram produced.

Surfactant-free synthesis of amphiphilic diblock copolymer nanoparticles via nitroxide-mediated emulsion polymerization

2005 ◽  
pp. 614 ◽  
Author(s):  
Guillaume Delaittre ◽  
Julien Nicolas ◽  
Catherine Lefay ◽  
Maud Save ◽  
Bernadette Charleux
Keyword(s):  
Emulsion Polymerization ◽  
Diblock Copolymer ◽  
Amphiphilic Diblock Copolymer

scholarly journals Tuning the membrane permeability of polymersome nanoreactors developed by aqueous emulsion polymerization-induced self-assembly

Nanoscale ◽  
2019 ◽  
Vol 11 (26) ◽  
pp. 12643-12654 ◽  
Author(s):  
Spyridon Varlas ◽  
Jeffrey C. Foster ◽  
Panagiotis G. Georgiou ◽  
Robert Keogh ◽  
Jonathan T. Husband ◽  
...  
Keyword(s):  
Membrane Permeability ◽  
Emulsion Polymerization ◽  
Self Assembly ◽  
Primary Amines ◽  
Cross Linking ◽  
Membrane Modification ◽  
Aqueous Emulsion

Membrane modification of epoxy-functionalized enzyme-loaded polymersomes using a series of primary amines and cross-linking diamines of increasing hydrophobicity resulted in functional nanoreactors with tunable permeability.

Universalization of the Phase Diagram for a Model Rod−Coil Diblock Copolymer

2008 ◽  
Vol 41 (18) ◽  
pp. 6809-6817 ◽  
Author(s):  
Bradley D. Olsen ◽  
Manas Shah ◽  
Venkat Ganesan ◽  
Rachel A. Segalman
Keyword(s):  
Phase Diagram ◽  
Diblock Copolymer

Block copolymers as polymeric stabilizers in non-aqueous emulsion polymerization

2011 ◽  
Vol 60 (11) ◽  
pp. 1563-1573 ◽  
Author(s):  
Leonard-I. Atanase ◽  
Gérard Riess
Keyword(s):  
Block Copolymers ◽  
Emulsion Polymerization ◽  
Aqueous Emulsion

scholarly journals Phase Diagram for a Diblock Copolymer Melt under Cylindrical Confinement

2006 ◽  
Vol 39 (2) ◽  
pp. 806-811 ◽  
Author(s):  
Weihua Li ◽  
Robert A. Wickham ◽  
Robert A. Garbary
Keyword(s):  
Phase Diagram ◽  
Diblock Copolymer

Novel reactive polymerizable nonyl phenol ethoxylate surfactants as emulsifier in non-aqueous emulsion polymerization

2014 ◽  
Vol 56 (6) ◽  
pp. 770-787 ◽  
Author(s):  
Ayman M. Atta ◽  
Amro K. F. Dyab ◽  
Hamad A. Al-Lohedan ◽  
Khaled A. AlJenady
Keyword(s):  
Emulsion Polymerization ◽  
Nonyl Phenol ◽  
Aqueous Emulsion ◽  
Nonyl Phenol Ethoxylate
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