A convenient access to fluorophosphonium triflate salts by electrophilic fluorination and anion exchange
Keyword(s):
One Pot
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The in situ one-pot electrophilic fluorination of phosphanes with NFSI followed by anion exchange with MeOTf gives highly electrophilic fluorophosphonium triflates – highly efficient catalysts for the synthesis of N-sulfonylamidines from amides.