A convenient access to fluorophosphonium triflate salts by electrophilic fluorination and anion exchange

Author(s):  
Chun-Xiang Guo ◽  
Sivathmeehan Yogendra ◽  
Rosa M. Gomila ◽  
Antonio Frontera ◽  
Felix Hennersdorf ◽  
...  

The in situ one-pot electrophilic fluorination of phosphanes with NFSI followed by anion exchange with MeOTf gives highly electrophilic fluorophosphonium triflates – highly efficient catalysts for the synthesis of N-sulfonylamidines from amides.

2017 ◽  
Vol 41 (19) ◽  
pp. 11225-11229 ◽  
Author(s):  
L. Santhosh ◽  
C. Srinivasulu ◽  
S. Durgamma ◽  
Girish Prabhu ◽  
Vommina V. Sureshbabu

Mild and highly efficient I2 and Et3N aided cyclodeselenization of in situ generated selenosemicarbazide is described to obtain 2-amino-1,3,4-oxadiazole peptidomimetics.


2010 ◽  
Vol 7 (4) ◽  
pp. 1196-1199
Author(s):  
Ahmed Benameur ◽  
Taoues Boumoud ◽  
Boudjemaa Boumoud ◽  
Salah Rhouati

The homocoupling of 2-chloro-carbaldehyde derivatives gave the corresponding 2,2’-biquinolines by using thein situgenerated reactive reagent Ni[(PPh3)]4. Several new 2-chloro-3-(1.3 dioxalan-2yl) quinoline derivatives are synthesized and structurally characterized. The overall structures of biquinoline derivatives are not planar.


2012 ◽  
Vol 2012 ◽  
pp. 1-6
Author(s):  
Parasa Hazarika ◽  
Pallab Pahari ◽  
Manash Jyoti Borah ◽  
Dilip Konwar

A novel catalytic system consisting of I2-SDS-H2O has been developed which cleaves 2,3-diaza-1,3-butadiene, 1-aza-1,3-butadienes, oximes and in presence of indoles in the medium uses the corresponding aldehyde products to produce bis(indolyl)alkanes in situ. This one pot simple and mild dual catalytic system works in water at room temperature under neutral conditions.


2018 ◽  
Vol 42 (6) ◽  
pp. 4215-4222 ◽  
Author(s):  
Xiaoqiang Du ◽  
Hailong Pan ◽  
Zhi Yang

A novel heterogeneous Co3O4/Co(OH)2 hybrid is prepared using a controllable facile one-pot hydrothermal reaction. The as-obtained hierarchical Co3O4/Co(OH)2 hybrids can serve as highly efficient electrocatalytic water oxidation catalysts for alkaline electrolytes.


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