Electronic and resonance Raman spectra of mixed-valence, linear-chain complexes of platinum and palladium with 1,2-diaminocycloalkanes (N–N), [ MII(N–N)2][ MIV(N–N)2X2]X4(X = halogen)

1982 ◽  
pp. 1851-1860 ◽  
Author(s):  
Robin J. H. Clark ◽  
Mohamedally Kurmoo ◽  
David N. Mountney ◽  
Hans Toftlund
Keyword(s):  
Raman Spectra ◽  
Linear Chain ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Chain Complexes ◽  
Resonance Raman Spectra

Electronic and Resonance Raman Spectra of Some New Mixed-Valence Compounds of Pt and Pd with a Metal-Halide Chain

1980 ◽  
Vol 35 (6) ◽  
pp. 676-679 ◽  
Author(s):  
G. C. Papavassiliou ◽  
D. Layek
Keyword(s):  
Raman Spectra ◽  
Linear Chain ◽  
Mixed Valence ◽  
Resonance Raman ◽  
Chain Structure ◽  
One Dimensional ◽  
Resonance Raman Spectra ◽  
The One ◽  
Mixed Valence Compounds ◽  
Linear Chain Structure

Abstract The electronic and resonance Raman spectra of new mixed-valence compounds of the type M2ʹ[M(L)X3][M(L)X5], where Mʹ = K, NH4, M = Pt or Pd, L = NH3 or pyridine, and X = Cl, Br or I, have been studied. The single-crystal polarized reflectance spectra indicate the one-dimensional semiconductor behaviour. The polarized resonance Raman spectra confirm the --M(II)--X-M(IV)-X linear chain structure, which is in accordance with the X-ray results. The polarization of M-N bands can be explained by the Snyder's theory (1971).

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