Preferential solvation of ions in mixed solvents. Part 2.—The solvent composition near the ion

1988 ◽  
Vol 84 (5) ◽  
pp. 1465 ◽  
Author(s):  
Yizhak Marcus
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvent Composition ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1986 ◽  
Vol 150 (1) ◽  
pp. 113-122 ◽  
Author(s):  
Dip Singh Gill ◽  
Suvarcha Chauhan ◽  
Mohinder Singh Chauhan
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents II

1983 ◽  
Vol 136 (136) ◽  
pp. 117-122 ◽  
Author(s):  
Dip Singh Gill ◽  
Reeta Nording
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1984 ◽  
Vol 140 (2) ◽  
pp. 139-148 ◽  
Author(s):  
Dip Singh Gill ◽  
Mohinder Singh Chauhan
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1984 ◽  
Vol 140 (2) ◽  
pp. 149-156 ◽  
Author(s):  
Dip Singh Gill ◽  
Mohinder Singh Chauhan
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Preferential Solvation of Ions in Mixed Solvents

1983 ◽  
Vol 134 (2) ◽  
pp. 205-214 ◽  
Author(s):  
Dip Singh Gill ◽  
Jagir Singh Cheema
Keyword(s):  
Preferential Solvation ◽  
Mixed Solvents ◽  
Solvation Of Ions

Conductance and viscosity measurements of some electrolytes in binary solvent mixtures of dimethylsulphoxide and dioxane at 25 °C

1991 ◽  
Vol 56 (9) ◽  
pp. 1813-1832 ◽  
Author(s):  
Vijay K. Syal ◽  
Puspha Bisht ◽  
Prakash C. Ranowt
Keyword(s):  
Preferential Solvation ◽  
Viscosity Coefficient ◽  
Solvent Composition ◽  
Binary Solvent ◽  
Viscosity Data ◽  
Solvent Mixtures ◽  
Ionic Conductance ◽  
Binary Solvent Mixtures ◽  
Viscosity Measurements ◽  
Solvation Of Ions

The conductance and viscosity measurements of Bu4NBPh4, Bu4NI, NaBPh4, Pr4NI, Et4NI, Me4NI, Bu4NNO3, KI, KClO4, NaClO4, KNO3, AgNO3, LiNO3 and NaBr have been carried out in the concentration range of (0-100) . 10-4 mol dm-3 for conductance and (0-250) . 10-4 mol dm-3 for viscosity in dimethylsulphoxide (DMSO) and DMSO + dioxane mixtures at 25°C. The conductance and viscosity data have been analysed by the Shedlovsky and Jones-Dole equations, respectively. The limiting ionic conductance (λi0), solvated radii (ri) and the ionic viscosity coefficient (B±) values have been evaluated. The variation of ri and B± value as a function of solvent composition has been interpreted in terms of preferential solvation of ions in these solvent mixtures.

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