Triplet‐State Zero‐Field‐Splitting Correlations in Substituted Molecules

1967 ◽  
Vol 46 (10) ◽  
pp. 3976-3983 ◽  
Author(s):  
B. Smaller ◽  
E. C. Avery ◽  
J. R. Remko
Keyword(s):  
Triplet State ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting

The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride

1996 ◽  
Vol 61 (9) ◽  
pp. 1285-1294 ◽  
Author(s):  
Karel Mach ◽  
Vojtech Varga ◽  
Günter Schmid ◽  
Jörg Hiller ◽  
Ulf Thewalt
Keyword(s):  
Crystal Structure ◽  
Triplet State ◽  
Structure Analysis ◽  
Crystal Structure Analysis ◽  
Epr Spectra ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
X Ray ◽  
Dimeric Structure

The X-ray crystal structure analysis of bis(1,3-dimethylcyclopentadienyl)titanium(III) chloride revealed that it is a centrosymmetric chlorine-bridged dimer [(η5-C5H3Me2)2Ti(μ-Cl)]2 (1) with the Ti-Ti distance of 3.9155(8) Å. Its skeleton is virtually identical with those of the [(η5-C5H5)2Ti(μ-Cl)]2 and [(η5-C5H4Me)2Ti(μ-Cl)]2 dimers. The solution EPR study proved that 1 remains a dimer in toluene whereas it dissociates in 2-methyltetrahydrofuran (MTHF) to give (η5-C5H3Me2)2TiCl . MTHF. The EPR spectra of frozen toluene solutions proved that 1 forms the triplet state whose g-tensor and zero-field splitting D are virtually the same as those of [(η5-C5H5)2Ti(μ-Cl)]2.

Zero‐Field Splitting of the Triplet State in Zinc Etioporphyrin

1972 ◽  
Vol 56 (8) ◽  
pp. 4073-4078 ◽  
Author(s):  
Martin Gouterman ◽  
B. S. Yamanashi ◽  
Alvin L. Kwiram
Keyword(s):  
Triplet State ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting
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