The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride
1996 ◽
Vol 61
(9)
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pp. 1285-1294
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X Ray
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The X-ray crystal structure analysis of bis(1,3-dimethylcyclopentadienyl)titanium(III) chloride revealed that it is a centrosymmetric chlorine-bridged dimer [(η5-C5H3Me2)2Ti(μ-Cl)]2 (1) with the Ti-Ti distance of 3.9155(8) Å. Its skeleton is virtually identical with those of the [(η5-C5H5)2Ti(μ-Cl)]2 and [(η5-C5H4Me)2Ti(μ-Cl)]2 dimers. The solution EPR study proved that 1 remains a dimer in toluene whereas it dissociates in 2-methyltetrahydrofuran (MTHF) to give (η5-C5H3Me2)2TiCl . MTHF. The EPR spectra of frozen toluene solutions proved that 1 forms the triplet state whose g-tensor and zero-field splitting D are virtually the same as those of [(η5-C5H5)2Ti(μ-Cl)]2.
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1975 ◽
Vol 67
(2)
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pp. 461-469
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1978 ◽
pp. 1536-1540
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1988 ◽
Vol 184
(3-4)
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pp. 209-219
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1976 ◽
pp. 266b-267
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1994 ◽
Vol 29
(3)
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pp. 373-378
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