Determination of structural parameters for ferrocenecarboxaldehyde using Fourier transform microwave spectroscopy

2005 ◽  
Vol 123 (5) ◽  
pp. 054317 ◽  
Author(s):  
Ranga Subramanian ◽  
Chandana Karunatilaka ◽  
Riley O. Schock ◽  
Brian J. Drouin ◽  
Paul A. Cassak ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Structural Parameters ◽  
Microwave Spectroscopy ◽  
Fourier Transform Microwave Spectroscopy

Fourier-transform microwave spectroscopy and determination of the three dimensional potential energy surface for Ar–CS

2014 ◽  
Vol 140 (10) ◽  
pp. 104310 ◽  
Author(s):  
Chisato Niida ◽  
Masakazu Nakajima ◽  
Yoshihiro Sumiyoshi ◽  
Yasuhiro Ohshima ◽  
Hiroshi Kohguchi ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Potential Energy ◽  
Potential Energy Surface ◽  
Energy Surface ◽  
Three Dimensional ◽  
Microwave Spectroscopy ◽  
Fourier Transform Microwave Spectroscopy

Analysis of Internal Rotation and Determination of the Heavy Atom Structure of anti-2,3-Dimethylthiirane by Fourier Transform Microwave Spectroscopy

1996 ◽  
Vol 51 (10-11) ◽  
pp. 1099-1106 ◽  
Author(s):  
Holger Hartwig ◽  
Helmut Dreizler
Keyword(s):  
Fourier Transform ◽  
Internal Rotation ◽  
Ground State ◽  
Heavy Atom ◽  
Microwave Spectroscopy ◽  
Rotational Spectrum ◽  
Advanced Technique ◽  
Fourier Transform Microwave Spectroscopy ◽  
Potential Parameters

Abstract We used the advanced technique of Fourier transform microwave spectroscopy to measure and assign the ground state rotational spectrum of anti-2,3-dimethylthiirane, and to analyse the internal rotation of the two methyl groups. The potential parameters obtained are V3 = 13.1678(21) and V12' = -1.6678(25) kJ/mol. The measurement and assignment of the 13C and 34S isotopomers in the ground state allowed to determine the molecular structure of the heavy atom frame using the Τs and Τ0 methods.

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