Benzonitrile and its van der Waals complexes studied in a free jet. II. Dynamics in the excited state: The effect of changing the degrees of freedom of partner molecules

1987 ◽  
Vol 86 (3) ◽  
pp. 1118-1124 ◽  
Author(s):  
Tohru Kobayashi ◽  
Okitsugu Kajimoto
Keyword(s):  
Excited State ◽  
Degrees Of Freedom ◽  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Free Jet

Benzonitrile and its van der Waals complexes studied in a free jet. I. The LIF spectra and the structure

1987 ◽  
Vol 86 (3) ◽  
pp. 1111-1117 ◽  
Author(s):  
Tohru Kobayashi ◽  
Kenji Honma ◽  
Okitsugu Kajimoto ◽  
Soji Tsuchiya
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Free Jet

Two-color photoionization of van der waals complexes of fluorobenzene in a supersonic free jet

1984 ◽  
Vol 107 (1) ◽  
pp. 22-26 ◽  
Author(s):  
Narishi Gonohe ◽  
Atsuo Shimizu ◽  
Haruo Abe ◽  
Naohiko Mikami ◽  
Mitsuo Ito
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Free Jet

scholarly journals Proton Tunneling In 5-Chlorotropolone-M1 (M = Kr, Xe, CH4) Van Der Waals Complexes

1995 ◽  
Vol 15 (2-4) ◽  
pp. 229-247
Author(s):  
Hiroshi Sekiya ◽  
Taiji Nakajima ◽  
Hidenori Hamabe ◽  
Akira Mori ◽  
Hitoshi Takeshita ◽  
...  
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Complexes ◽  
Excitation Spectra ◽  
Fluorescence Excitation ◽  
Proton Tunneling ◽  
Tunneling Splitting ◽  
Free Jet ◽  
Tunneling Splittings ◽  
Fluorescence Excitation Spectra ◽  
Intramolecular Motions

The S1-S0 fluorescence excitation spectra of 5-chlorotropolone-M1 (M = Kr, Xe, CH4) van der Waals (vdW) complexes in the region near the electronic origin have been measured in a supersonic free jet to investigate the effect of the vdW interactions on proton tunneling. Tunneling splittings have been observed in the vdW vibrations as well as in the 000 transitions of the Kr and Xe complexes. The 000 tunneling splitting of the 5-chlorotropolone-(CH4)1 complex is significantly smaller than those of the Kr and Xe complexes. It has been suggested that the vdW vibrations couple with intramolecular motions, leading to a higher potential energy barrier to tunneling in the CH4 complex. The results of the 5- chlorotropolone complexes have been compared to those of the tropolone complexes.

Partitioning of interaction energy in van der Waals complexes involving excited state species: The He(1S)+Cl2(B 3Πu) interaction

1995 ◽  
Vol 103 (23) ◽  
pp. 10116-10127 ◽  
Author(s):  
Sl/awomir M. Cybulski ◽  
Rudolf Burcl ◽  
Grzegorz Chal/asiński ◽  
M. M. Szczȩśniak
Keyword(s):  
Excited State ◽  
Interaction Energy ◽  
Van Der Waals ◽  
Van Der Waals Complexes
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