The PI4+ cation has an extremely large negative 31P nuclear magnetic resonance chemical shift, due to spin–orbit coupling: A quantum-chemical prediction and its confirmation by solid-state nuclear magnetic resonance spectroscopy

1999 ◽  
Vol 110 (8) ◽  
pp. 3897-3902 ◽  
Author(s):  
Martin Kaupp ◽  
Christoph Aubauer ◽  
Günter Engelhardt ◽  
Thomas M. Klapötke ◽  
Olga L. Malkina
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