Lewis-Base Adducts of Main Group 1 Metal-Compounds. XIII. Synthesis and Structures of Some Pyridine Base Lithium Bromide and Iodide Adducts
Keyword(s):
X Ray
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The syntheses and single-crystal X-ray structure determinations of adducts of the lithium(I) halides with the following stoichiometries are reported: 1 : 3 lithium(I) bromide, iodide/ pyridine, monomers; 1 : 2 lithium(I) bromide/ quinoline and lithium(I) iodide/ quinaldine , both as [L2LiX2LiL2] dimers ; and 1 : 1� lithium(I) iodide/2,4,6-trimethylpyridine, 'step' tetramer.