Five-Coordinate Cationic Rhodium(I) Carbonyl Complexes with Heterocyclic Nitrogen Donor Ligands

1980 ◽  
Vol 10 (6) ◽  
pp. 553-567 ◽  
Author(s):  
D. K. Dutta ◽  
M. M. Singh
Keyword(s):  
Donor Ligands ◽  
Carbonyl Complexes ◽  
Nitrogen Donor Ligands ◽  
Heterocyclic Nitrogen ◽  
Nitrogen Donor

Cyclometallation reactions. XIII. Reactions of phenyl-substituted heterocyclic nitrogen-donor ligands

1975 ◽  
Vol 28 (6) ◽  
pp. 1259 ◽  
Author(s):  
MI Bruce ◽  
BL Goodall ◽  
I Matsuda
Keyword(s):  
Donor Ligands ◽  
Nitrogen Donor Ligands ◽  
Heterocyclic Nitrogen ◽  
Nitrogen Donor

The preparation of some metallated complexes of manganese or rhenium derived from 2-phenylpyridine,1,4-diphenylquinoxaline, 1- phenylpyrazole, 4-phenylpyrimidine, 1,4-diphenylphthalazineand 2,5- diphenyloxazole is described.

The preparation of stable dimercury(I)-nitrogen donor complexes

1974 ◽  
Vol 27 (6) ◽  
pp. 1199 ◽  
Author(s):  
DL Kepert ◽  
D Taylor
Keyword(s):  
Donor Ligands ◽  
Stable Complex ◽  
Nitrogen Donor Ligands ◽  
Heterocyclic Nitrogen ◽  
Nitrogen Donor ◽  
Base Strength

A series of dimercury(1) complexes of the type [Hg2L2] [ClO4]2 has been prepared with heterocyclic nitrogen donor ligands. Complexes with 2-ethylpyridine and 4-benzylpyridine were of the form [Hg2L3.7] [ClO4]2 and [Hg2L4] [ClO4]2 respectively. The formation of a stable complex is found to be dependent on the effective base strength of the ligand.

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