Syntheses, structures, and properties of two- and three-dimensional coordination polymers based on bis(imidazole) and glutarate ligands

2015 ◽  
Vol 68 (7) ◽  
pp. 1213-1223 ◽  
Author(s):  
Zhi Yang ◽  
Shan-Shan Han ◽  
Ling-Yun Zheng ◽  
Yan-Fen Peng ◽  
Bao-Long Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Structures And Properties

Three-dimensional lanthanide–silver heterometallic coordination polymers: syntheses, structures and properties

CrystEngComm ◽  
2010 ◽  
Vol 12 (10) ◽  
pp. 3267 ◽  
Author(s):  
Man-Sheng Chen ◽  
Zhi Su ◽  
Min Chen ◽  
Shui-Sheng Chen ◽  
Yi-Zhi Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Structures And Properties ◽  
Heterometallic Coordination Polymers

Three Coordination Polymers Built by Methoxyphenyl Imidazole Dicarboxylate: Solvothermal Syntheses, Crystal Structures, and Properties

2015 ◽  
Vol 68 (6) ◽  
pp. 956 ◽  
Author(s):  
Ming-An Dang ◽  
Zi-Feng Li ◽  
Ying Liu ◽  
Gang Li
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Photoluminescence Properties ◽  
X Ray Diffraction ◽  
Bridging Ligands ◽  
X Ray ◽  
Structures And Properties ◽  
Solvothermal Syntheses ◽  
Lattice Polymer ◽  
Imidazole Dicarboxylate

Three coordination polymers [Sr(p-H2MOPhIDC)2]n (1) (p-H3MOPhIDC = 2-p-methoxyphenyl-1H-imidazole-4,5-dicarboxylic acid), {[Cd2(p-HMOPhIDC)2(4,4′-bipy)]⋅H2O}n (4,4′-bipy = 4,4′-bipyridine) (2), and [Zn(p-HMOPhIDC)(4,4′-bipy)]n (3) have been solvothermally synthesized, and structurally characterized by single-crystal X-ray diffraction. Polymer 1 indicates a three-dimensional framework, which can be simplified as a 6-connected lattice. Polymer 2 is also a three-dimensional framework, and contains mixed bridging ligands HMOPhIDC2– and 4,4′-bipy. Polymer 3 exhibits a sheet structure bearing infinite rectangles. The coordination modes of the p-H3MOPhIDC ligand, and the thermal and solid-state photoluminescence properties of the polymers have been investigated as well.

Two- and three-dimensional lanthanide-based coordination polymers assembled by the synergistic effect of various lanthanide radii and flexibility of a new binicotinate-containing ligand: in situ synthesis, structures, and properties

RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 2239-2248 ◽  
Author(s):  
Baoming Ji ◽  
Dongsheng Deng ◽  
Junying Ma ◽  
Chaowei Sun ◽  
Bin Zhao
Keyword(s):  
Synergistic Effect ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
In Situ Synthesis ◽  
Coordination Modes ◽  
Design And Synthesis ◽  
Structural Types ◽  
Lanthanide Contraction ◽  
Structures And Properties

The design and synthesis of ten novel coordination polymers was investigated. They have three structural types from 3D to 2D due to the synergistic effect of lanthanide contraction with diverse coordination modes and conformations of the ligand.

Three-dimensional 3d-4f heterometallic coordination polymers: syntheses, structures and properties

2011 ◽  
Vol 23 (1-2) ◽  
pp. 117-124 ◽  
Author(s):  
Man-Sheng Chen ◽  
Yue Zhao ◽  
Taka-Aki Okamura ◽  
Zhi Su ◽  
Wei-Yin Sun ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Structures And Properties ◽  
Heterometallic Coordination Polymers

Synthesis, Structures and Properties of Two New Three-Dimensional Ce(III) Coordination Polymers with 2,2'-Bipyridine-4,4'-Dicarboxylic Acid

2013 ◽  
Vol 750-752 ◽  
pp. 1708-1711
Author(s):  
Rui Ping Zheng ◽  
Hui Yuan Chen ◽  
Jun Jie He ◽  
He Ping Zeng
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Dimethyl Formamide ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Space Group ◽  
Solvothermal Condition ◽  
Structures And Properties

Two new Ce(III) coordination polymers formulated as Ce(bpdc)(Hbpdc)(DMF)2 (1) and [Ce2(bpdc)3(DMF)2(H2O)4]·2DMF (2) (H2bpdc = 2,2'-bipyridine-4,4'-dicarboxylic acid, DMF = N,N-Dimethyl formamide) have been synthesized under solvothermal condition and characterized by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic, space group C2/c with a = 2.2520(2), b = 1.17787(12), c = 1.16128(11) nm, α = 90, β = 95.5600(10), γ = 90°, V = 3.0658(5) nm3, Z = 4, Mr = 771.70, Dc = 1.672×10-9 g/cm3. Compound 2 crystallizes in triclinic, space group Pwith a = 1.00610(10), b = 1.17219(11), c = 1.36891(14) nm, α = 66.9340(10), β = 87.182(2), γ = 76.2570(10) °, V = 1.4411(2) nm3, Z = 1, Mr = 1371.25, Dc = 1.580×10-9 g/cm3. Both compounds exhibit 3D Ce(III)–organic frameworks. Furthermore, thermal stability and luminescent properties were also investigated. CCDC:(1)913670, (2)909563.

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