KINETIC MODELING OF THE CATALYTIC OXIDATION OF BENZO(A)PYRENE

1980 ◽  
Vol 7 (1-3) ◽  
pp. 169-183 ◽  
Author(s):  
HOWARD L. GREENE ◽  
ARVIND KAPOOR
Keyword(s):  
Catalytic Oxidation ◽  
Kinetic Modeling

scholarly journals Cyclometalated Iridium(III) Complexes Containing Benzoxazole Derivatives and Different Ancillary Ligands for Catalytic Oxidation of Toluene

Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 118 ◽  
Author(s):  
Kelvin Chen ◽  
Pei-Chun Liu ◽  
Tsun-Ren Chen ◽  
Jhy-Der Chen
Keyword(s):  
Catalytic Oxidation ◽  
Kinetic Modeling ◽  
Processing Time ◽  
Pyridine Derivatives ◽  
Turnover Number ◽  
Edge Structure ◽  
Ancillary Ligands ◽  
X Ray ◽  
Environmentally Friendly Process ◽  
X Ray Absorption

A series of cyclometalated iridium(III) complexes that have the general formula [(C^N)2Ir(NR)(X)] (C^N = monoanionic bidentate cyclometalating ligands; NR = pyridine derivatives; X = Cl− or I−) are designed, prepared, and applied for the transformation of toluene to benzaldehyde using a clean, highly efficient, and environmentally-friendly process. The activation energies that are needed for the catalytic oxidation of toluene when using these complexes as catalysts are quite low: between 22.9 and 30.8 kcal mol−1. The catalytic frequencies (TOF) are fairly high (up to 7.0 × 102 h−1) with excellent reliability, and the turnover number (TON) can reach 4.2 × 103 after 6 h of processing time. Catalytic tests, X-ray absorption near-edge structure (XANES), and kinetic modeling are used to derive detailed insights into the characteristics of the catalysts and their effects on the reactions that are featured in the catalytic oxidation of toluene.

Catalytic oxidation of ethylbenzene: kinetic modeling, mechanism, and implications

2021 ◽  
Author(s):  
Ashish P. Unnarkat ◽  
Jaimish Sonani ◽  
Jay Baldha ◽  
Shivani Agarwal ◽  
Kevin Manvar ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Kinetic Modeling ◽  
Oxidation Of Ethylbenzene

Allene oxidation in jet-stirred reactor : a kinetic modeling study

1990 ◽  
Vol 87 ◽  
pp. 1159-1172 ◽  
Author(s):  
P Dagaut ◽  
M Cathonnet ◽  
B Aboussi ◽  
JC Boettner
Keyword(s):  
Kinetic Modeling ◽  
Stirred Reactor ◽  
Allene Oxidation ◽  
Modeling Study

Estimation and Kinetic Modeling of Human Arm using Wearable Robot Arm

2016 ◽  
Vol 136 (4) ◽  
pp. 254-262 ◽  
Author(s):  
Takahiro Yamazaki ◽  
Sho Sakaino ◽  
Toshiaki Tsuji
Keyword(s):  
Kinetic Modeling ◽  
Robot Arm ◽  
Wearable Robot ◽  
Human Arm
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