Catalytic oxidation of ethylbenzene: kinetic modeling, mechanism, and implications

2021 ◽  
Author(s):  
Ashish P. Unnarkat ◽  
Jaimish Sonani ◽  
Jay Baldha ◽  
Shivani Agarwal ◽  
Kevin Manvar ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Kinetic Modeling ◽  
Oxidation Of Ethylbenzene

Catalytic Oxidation of Ethylbenzene to Acetophenone Using Mg-Al Hydrotalcite-Supported MnO4-Catalyst

2012 ◽  
Vol 29 (9) ◽  
pp. 1017
Author(s):  
Yifan WANG ◽  
Weiyou ZHOU ◽  
Xiao FANG ◽  
Qun CHEN
Keyword(s):  
Catalytic Oxidation ◽  
Oxidation Of Ethylbenzene

scholarly journals Cyclometalated Iridium(III) Complexes Containing Benzoxazole Derivatives and Different Ancillary Ligands for Catalytic Oxidation of Toluene

Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 118 ◽  
Author(s):  
Kelvin Chen ◽  
Pei-Chun Liu ◽  
Tsun-Ren Chen ◽  
Jhy-Der Chen
Keyword(s):  
Catalytic Oxidation ◽  
Kinetic Modeling ◽  
Processing Time ◽  
Pyridine Derivatives ◽  
Turnover Number ◽  
Edge Structure ◽  
Ancillary Ligands ◽  
X Ray ◽  
Environmentally Friendly Process ◽  
X Ray Absorption

A series of cyclometalated iridium(III) complexes that have the general formula [(C^N)2Ir(NR)(X)] (C^N = monoanionic bidentate cyclometalating ligands; NR = pyridine derivatives; X = Cl− or I−) are designed, prepared, and applied for the transformation of toluene to benzaldehyde using a clean, highly efficient, and environmentally-friendly process. The activation energies that are needed for the catalytic oxidation of toluene when using these complexes as catalysts are quite low: between 22.9 and 30.8 kcal mol−1. The catalytic frequencies (TOF) are fairly high (up to 7.0 × 102 h−1) with excellent reliability, and the turnover number (TON) can reach 4.2 × 103 after 6 h of processing time. Catalytic tests, X-ray absorption near-edge structure (XANES), and kinetic modeling are used to derive detailed insights into the characteristics of the catalysts and their effects on the reactions that are featured in the catalytic oxidation of toluene.

KINETIC MODELING OF THE CATALYTIC OXIDATION OF BENZO(A)PYRENE

1980 ◽  
Vol 7 (1-3) ◽  
pp. 169-183 ◽  
Author(s):  
HOWARD L. GREENE ◽  
ARVIND KAPOOR
Keyword(s):  
Catalytic Oxidation ◽  
Kinetic Modeling

Catalytic Oxidation of Ethylbenzene in the Liquid Phase

1933 ◽  
Vol 25 (11) ◽  
pp. 1286-1287 ◽  
Author(s):  
C. E. Senseman ◽  
J. J. Stubbs
Keyword(s):  
Liquid Phase ◽  
Catalytic Oxidation ◽  
Oxidation Of Ethylbenzene

Synergistic Catalytic Oxidation of Ethylbenzene to Acetophenone by Metallophthalocyanine Intercalated Layered Double Hydroxide with Oxygen

2018 ◽  
Vol 3 (2) ◽  
pp. 566-572 ◽  
Author(s):  
Weiyou Zhou ◽  
Xuan Dai ◽  
Yong Chen ◽  
Fu'an Sun ◽  
Mingyang He ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Layered Double Hydroxide ◽  
Oxidation Of Ethylbenzene ◽  
Double Hydroxide
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