Estimation of measurement uncertainty associated to the determination of pesticide residues: A case study

2012 ◽  
Vol 47 (8) ◽  
pp. 804-813 ◽  
Author(s):  
Patrizia Stefanelli ◽  
Danilo Attard Barbini ◽  
Silvana Girolimetti ◽  
Roberto Dommarco
2011 ◽  
Vol 201-203 ◽  
pp. 1642-1648
Author(s):  
Jin Xing Wang ◽  
Xiang Qian Jiang ◽  
Pan Wang

The improved GPS (Geometrical Product Specification) system uses uncertainty as an economic tool to enable optimum allocation of resource amongst specification, manufacturing and verification. For a given GPS standard-chain, the key question is to calculate the compliance uncertainty. The determination of compliance uncertainty is a complex question because specification uncertainty and measurement uncertainty arise from many causes and propagate through the GPS standard-chain. A calculation method for compliance uncertainty of GPS standard-chain is proposed in this article. According to ISO 17450–2, a GPS process should be either in default state or special state. The biggest difference between the two states is that whether the specification operator is accordant with the verification operator. Aiming at the two states, the flow for the computation of compliance uncertainty is given respectively, and a case study is applied in default state. Results show it enables to generate compliance uncertainty on the verification of a GPS standard-chain, which makes the acceptance or refusal of GPS characteristic can be conducted in a quantitative way, so the veracity of verification could be improved.


TAPPI Journal ◽  
2012 ◽  
Vol 11 (10) ◽  
pp. 9-17
Author(s):  
ALESSANDRA GERLI ◽  
LEENDERT C. EIGENBROOD

A novel method was developed for the determination of linting propensity of paper based on printing with an IGT printability tester and image analysis of the printed strips. On average, the total fraction of the surface removed as lint during printing is 0.01%-0.1%. This value is lower than those reported in most laboratory printing tests, and more representative of commercial offset printing applications. Newsprint paper produced on a roll/blade former machine was evaluated for linting propensity using the novel method and also printed on a commercial coldset offset press. Laboratory and commercial printing results matched well, showing that linting was higher for the bottom side of paper than for the top side, and that linting could be reduced on both sides by application of a dry-strength additive. In a second case study, varying wet-end conditions were used on a hybrid former machine to produce four paper reels, with the goal of matching the low linting propensity of the paper produced on a machine with gap former configuration. We found that the retention program, by improving fiber fines retention, substantially reduced the linting propensity of the paper produced on the hybrid former machine. The papers were also printed on a commercial coldset offset press. An excellent correlation was found between the total lint area removed from the bottom side of the paper samples during laboratory printing and lint collected on halftone areas of the first upper printing unit after 45000 copies. Finally, the method was applied to determine the linting propensity of highly filled supercalendered paper produced on a hybrid former machine. In this case, the linting propensity of the bottom side of paper correlated with its ash content.


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