Diastereoselective cycloaddition of tosylpropadiene to azomethine ylides, derived from proline and carbonyl compounds: an experimental and DFT study

2021 ◽  
pp. 1-5
Author(s):  
Alexander V. Stepakov ◽  
Alexander S. Filatov ◽  
Vitali M. Boitsov ◽  
Stanislav V. Lozovskiy
Keyword(s):  
Carbonyl Compounds ◽  
Dft Study ◽  
Azomethine Ylides

scholarly journals C–H functionalization of cyclic amines: redox-annulations with α,β-unsaturated carbonyl compounds

2015 ◽  
Vol 51 (53) ◽  
pp. 10648-10651 ◽  
Author(s):  
YoungKu Kang ◽  
Matthew T. Richers ◽  
Conrad H. Sawicki ◽  
Daniel Seidel
Keyword(s):  
Carboxylic Acid ◽  
Carbonyl Compounds ◽  
Azomethine Ylides ◽  
Unsaturated Ketones ◽  
Cyclic Amines

Pyrrolidine and related amines undergo carboxylic acid promoted redox-annulations with α,β-unsaturated ketonesviathe intermediacy of conjugated azomethine ylides.

The reaction of secondary α-amino acids with carbonyl compounds. Properties of the intermediate azomethine ylides. Oxazolidine formation versus 1.4-prototropy.

1987 ◽  
Vol 28 (48) ◽  
pp. 6077-6080 ◽  
Author(s):  
Moustafa F. Aly ◽  
Harriet Ardill ◽  
Ronald Grigg ◽  
Stephanie Leong-Ling ◽  
Shuleewan Rajviroongit ◽  
...  
Keyword(s):  
Amino Acids ◽  
Carbonyl Compounds ◽  
Azomethine Ylides
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