Effect of preparation conditions on the electro-optical performance and the polymer morphology of polymer-dispersed liquid crystals with polyhedral oligomeric silsesquioxane (POSS) microstructure

Author(s):  
Ping Yu ◽  
Yuzhen Zhao ◽  
Zemin He ◽  
Huimin Zhang ◽  
Yang Zhao ◽  
...  
2001 ◽  
Vol 694 ◽  
Author(s):  
Michael J. Escuti ◽  
Gregory P. Crawford

AbstractWe introduce and explore two- and three-dimensional lattices formed in Holographic-Polymer Dispersed Liquid Crystals (H-PDLC) materials, which exhibit an electrically controllable index modulation in multiple dimensions. As electro-optically active holograms, these materials exhibit fast dynamic switching phenomena (~100 microseconds), and are simple to fabricate. While many applications have been proposed for these materials, almost all are based on one-dimensional index modulations in various grating regimes. However, constraints in additional dimensions lead to a much greater sensitivity of the polymer morphology to monomer functionality, exposure irradiance, and grating pitch. In an effort to begin to understand this relationship, two-dimensional triangle lattices were created using two monomeric blends exposed over a range of powers. Final diffraction efficiency (Bragg regime), saturation voltage, and polymer morphology were examined from the resulting triangle lattices. Three- dimensional lattices are discussed and a six-beam holographic method is proposed. Photonic crystal applications are envisioned where the pseudo-bandgap can be electrically controlled.


2001 ◽  
Vol 709 ◽  
Author(s):  
Michael J. Escuti ◽  
Gregory P. Crawford

ABSTRACTWe introduce and explore two- and three-dimensional lattices formed in Holographic-Polymer Dispersed Liquid Crystals (H-PDLC) materials, which exhibit an electrically controllable index modulation in multiple dimensions. As electro-optically active holograms, these materials exhibit fast dynamic switching phenomena (~100 microseconds), and are simple to fabricate. While many applications have been proposed for these materials, almost all are based on one-dimensional index modulations in various grating regimes. However, constraints in additional dimensions lead to a much greater sensitivity of the polymer morphology to monomer functionality, exposure irradiance, and grating pitch. In an effort to begin to understand this relationship, two-dimensional triangle lattices were created using two monomeric blends exposed over a range of powers. Final diffraction efficiency (Bragg regime), saturation voltage, and polymer morphology were examined from the resulting triangle lattices. Three-dimensional lattices are discussed and a six-beam holographic method is proposed. Photonic crystal applications are envisioned where the pseudo-bandgap can be electrically controlled.


Author(s):  
Cheryll Lei E. Mahinay ◽  
Claire M. Macale ◽  
Fairland F. Amos ◽  
Zenaida B. Domingo ◽  
Leonorina G. Cada

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