optical characterization
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Author(s):  
Ryosuke Ohnuki ◽  
Naoki Kunimoto ◽  
Yukikazu Takeoka ◽  
Shinya Yoshioka

Biomimetics ◽  
2022 ◽  
Vol 7 (1) ◽  
pp. 13
Author(s):  
Yuxiang Zhang ◽  
Hortense Le Ferrand

Bioinspired self-shaping is an approach used to transform flat materials into unusual three-dimensional (3D) shapes by tailoring the internal architecture of the flat material. Bioinspiration and bioinspired materials have a high potential for fostering sustainable development, yet are often fashioned out of expensive and synthetic materials. In this work, we use bioinspiration to endow clay with self-shaping properties upon drying. The composites created are based on clay and starch, and the internal architecture is built using celery fibers. The viscosity, shrinkage, and bending of the architected composite monolayers are studied for several compositions by measuring penetration depth and using optical characterization methods. Bilayer structures inspired from plants are then processed using a simple hand layup process to achieve bending, twisting, and combinations of those after drying. By layering a mixture of 32 vol% clay, 25.8 vol% starch, and 42.2 vol% water with 40 wt% embedded aligned celery fibers, it is possible to obtain the desired shape change. The work presented here aims at providing a simple method for teaching the concept of bioinspiration, and for creating new materials using only clay and plant-based ingredients. Rejuvenating clay with endowed self-shaping properties could further expand its use. Furthermore, the materials, methods, and principles presented here are affordable, simple, largely applicable, and could be used for sustainable development in the domain of education as well as materials and structures.


2022 ◽  
Author(s):  
Philip Lax ◽  
Skye Elliott ◽  
Stanislav Gordeyev ◽  
Sergey B. Leonov

Molecules ◽  
2022 ◽  
Vol 27 (1) ◽  
pp. 280
Author(s):  
Navindra Keerthisinghe ◽  
Matthew S. Christian ◽  
Anna A. Berseneva ◽  
Gregory Morrison ◽  
Vladislav V. Klepov ◽  
...  

The solvothermal synthesis, structure determination and optical characterization of five new metastable halometallate compounds, [1,10-phenH][Pb3.5I8] (1), [1,10-phenH2][Pb5I12]·(H2O) (2), [1,10-phen][Pb2I4] (3), [1,10-phen]2[Pb5Br10] (4) and [1,10-phenH][SbI4]·(H2O) (5), are reported. The materials exhibit rich structural diversity and exhibit structural dimensionalities that include 1D chains, 2D sheets and 3D frameworks. The optical spectra of these materials are consistent with bandgaps ranging from 2.70 to 3.44 eV. We show that the optical behavior depends on the structural dimensionality of the reported materials, which are potential candidates for semiconductor applications.


2022 ◽  
Author(s):  
Raveendra Melavanki ◽  
Vijaya Kumar ◽  
N L Ramesh ◽  
Diksha Singh ◽  
Daruka Prasad B ◽  
...  

Abstract Quinoline Yellow (QY) with the scientific name [sodium 2-(2, 3-dihydro-1,3-dioxo-1H-inden-2-yl) quinoline-6,8-disulfonate] (SQDS) is investigated for its sensing properties as fluorochemosensors and its NLO applications. Pure SQDS is doped with copper ferrite and cerium oxide nanoparticles and studied for changes in spectral results. Change in absorption spectrum is observed depending on the polarity of solvents. Intensity of fluorescence also varies with different type of solvents. Optical characterization for SQDS is carried out via various spectroscopic techniques including UV-VIS spectroscopy, FTIR spectroscopy, Scanning Electron Microscopy and Photo Luminescence (PL) spectroscopy. Optical parameters like extinction coefficient, refractive index and bandgap energy are determined from absorption spectrum for both solution and film samples. XRD characterization is also performed for QY and for nanoparticle doped QY. For investigating Non-Linear optical (NLO) application of QY, films are prepared and optical imaging is performed via Atomic Force Microscopy (AFM). Characterization results are analysed and predicted for application in non-linear optics.


2021 ◽  
Author(s):  
Jiri Vohanka ◽  
Ivan Ohlidal ◽  
Vilma Buršíková ◽  
Petr Klapetek ◽  
Nupinder Jeet Kaur

ACS Omega ◽  
2021 ◽  
Author(s):  
Lenka Pribusová Slušná ◽  
Tatiana Vojteková ◽  
Jana Hrdá ◽  
Helena Pálková ◽  
Peter Siffalovic ◽  
...  

2021 ◽  
Vol 400 (1) ◽  
pp. 2100150
Author(s):  
Kalpana Sharma ◽  
Raveendra Melavanki ◽  
Basappa C Yallur ◽  
Raviraj Kusanur ◽  
N R Patil

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