Partial Oxidation of Alcohols to Aldehydes and Ketones Under Mild Conditions

2004 ◽  
Vol 34 (10) ◽  
pp. 1753-1758 ◽  
Author(s):  
Guang Qian ◽  
Rui Zhao ◽  
Gaomeng Lu ◽  
Yanxing Qi ◽  
Jishuan Suo
Keyword(s):  
Partial Oxidation ◽  
Mild Conditions ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones

Partial Oxidation of Alcohols to Aldehydes and Ketones under Mild Conditions.

ChemInform ◽  
2004 ◽  
Vol 35 (41) ◽  
Author(s):  
Guang Qian ◽  
Rui Zhao ◽  
Gaomeng Lu ◽  
Yanxing Qi ◽  
Jishuan Suo
Keyword(s):  
Partial Oxidation ◽  
Mild Conditions ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones

scholarly journals Fe(II)-phthalocyanine supported on chitosan aerogel as a catalyst for oxidation of alcohols and alkyl arenes

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Fatemeh Azimi ◽  
Ahmad Poursattar Marjani ◽  
Sajjad Keshipour
Keyword(s):  
Aspect Ratio ◽  
Heterogeneous Catalyst ◽  
High Aspect Ratio ◽  
Room Temperature ◽  
Oxidation Reactions ◽  
Mild Conditions ◽  
Oxidation Of Alcohols ◽  
Aromatic Alcohols ◽  
Aldehydes And Ketones ◽  
Low Toxicity

AbstractManipulation of materials is considered as one of the eminent strategies to create desirable catalysts. In this regard, increasing surface area and decreasing dimensions of catalysts have been widely employed on account of effectiveness of these methods. Herein, aerogel form of chitosan as a sustainable, and high aspect ratio compound is employed as a green support for the catalytic purposes. Chitosan aerogel was modified with Fe(II)-phthalocyanine to produce a heterogeneous catalyst for oxidation reactions. The synthesized catalyst promoted the oxidation reactions of alcohols and alkyl arenes to the corresponding aldehydes and ketones using H2O2 as an oxidant in 24 h. The reactions for aliphatic and aromatic alcohols gave turnover numbers of 106–109 at 80 °C and 106–117 at room temperature, respectively. The oxidations of alkyl arenes were carried out with turnover numbers laying in the range of 106–117 at 100 °C. The low toxicity, inexpensive nature, and recycling possibility of the catalyst accompanied by the reaction mild conditions, clean oxidant, and excellent yields offer chitosan aerogel modified with Fe(II)-phthalocyanine as a promising catalyst for oxidation reactions.

Efficient Mn–Cu and Mn–Co–TEMPO-catalysed oxidation of alcohols into aldehydes and ketones by oxygen under mild conditions

2001 ◽  
Vol 42 (38) ◽  
pp. 6651-6653 ◽  
Author(s):  
Andrea Cecchetto ◽  
Francesca Fontana ◽  
Francesco Minisci ◽  
Francesco Recupero
Keyword(s):  
Mild Conditions ◽  
Catalysed Oxidation ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones

ChemInform Abstract: Efficient Mn-Cu and Mn-Co-TEMPO Catalyzed Oxidation of Alcohols into Aldehydes and Ketones by Oxygen under Mild Conditions.

ChemInform ◽  
2010 ◽  
Vol 32 (49) ◽  
pp. no-no
Author(s):  
Andrea Cecchetto ◽  
Francesca Fontana ◽  
Francesco Minisci ◽  
Francesco Recupero
Keyword(s):  
Mild Conditions ◽  
Oxidation Of Alcohols ◽  
Aldehydes And Ketones ◽  
Catalyzed Oxidation
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