A comparative study of the surface contaminated layer formed by chemical reaction between ceramic-mold and titanium aluminum alloy castings or titanium alloy castings were carried out. The morphology, thickness and hardness of the surface contaminated layer were characterized by means of metalloscopy and microhardness measurement. The results show that surface contaminated layers formed between Ti-Al alloy castings and ceramic-mold, also formed between Ti alloy castings and ceramic-mold. The surface contaminated layers of Ti-Al alloy castings were continuous and compact, their thickness was about 0~90 μm. The surface contaminated layers of titanium alloy castings were not even, their thickness was 0~900 μm. Titanium alloy is more liable to react with the ceramic -mold than the Ti-Al alloy.
Investigation on microstructure and fracture behaviour of titanium alloy castings