Original disorder–order transition related to electronic and magnetic properties in the thermoelectric misfit phase [Ca2CoO3][CoO2]1.62
2008 ◽
Vol 64
(6)
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pp. 676-683
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Keyword(s):
A structural phase transition is shown around 400 K for the thermoelectric lamellar misfit cobalt oxide [Ca2CoO3][CoO2]1.62. This transition is related to a rearrangement of the central [CoO] layer of the [Ca2CoO3] slab of this structure, characterized by a commensurate intrinsic modulation q 2 = 2\over 3a * − 1\over 3c *. The partial residual disorder related to split Co and O atomic sites along the misfit b direction disappears and one can describe this layer with its triple chains as a modulated configuration with a regular and not distorted periodicity along b. This phase transition is associated with small changes observed in the transport and magnetic properties as a function of temperature.
1997 ◽
Vol 9
(8)
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pp. 1729-1741
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2000 ◽
Vol 62
(21)
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pp. 14197-14206
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Keyword(s):
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2013 ◽
Vol 430
◽
pp. 012108
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Keyword(s):
2006 ◽
Vol 179
(3)
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pp. 605-612
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Keyword(s):