μ-Oxido-bis({4,4′-dibromo-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}manganese(III))

2007 ◽  
Vol 63 (11) ◽  
pp. m2771-m2771 ◽  
Author(s):  
Ying Liu ◽  
Jianmin Dou ◽  
Meiju Niu ◽  
Xianxi Zhang
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Basal Plane ◽  
Rotation Axis ◽  
The Other ◽  
Coordination Geometry ◽  
Apical Position

The title compound, [Mn2(C16H12Br2N2O2)2O], is an unusual dinuclear manganese(III) complex. Each MnIII ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Mn atom is coordinated by two N atoms and two O atoms of the Schiff base ligand. The apical position is occupied by a bridging O2− ion, which links to the other MnIII ion in the complex; this bridging O atom lies on a twofold rotation axis.

scholarly journals {2-[(2-Aminocyclohexyl)iminomethyl]phenolato}dioxidovanadium(V)

2012 ◽  
Vol 68 (4) ◽  
pp. m476-m476
Author(s):  
Xin-Zhi Sun
Keyword(s):  
Schiff Base ◽  
Hydrogen Bonds ◽  
Schiff Base Ligand ◽  
Basal Plane ◽  
The Other ◽  
Apical Position ◽  
Tridentate Schiff Base

In the title dioxidovanadium complex, [V(C13H17N2O)O2], the VVatom is in a square-based pyramidal coordination: the basal plane is defined by the phenolate O, imine N and amine N atoms of the tridentate Schiff base ligand, and by one oxide O atom. The apical position is occupied by the other oxide O atom. In the crystal, molecules are connected by N—H...O and N—H...(O,O) hydrogen bonds, forming a tetramer.

scholarly journals Di-μ-hydroxido-bis[hemiaqua(N,N,N′,N′-tetramethylethane-1,2-diamine)copper(II)] bis(tetrafluoridoborate)

2012 ◽  
Vol 68 (6) ◽  
pp. m784-m784
Author(s):  
Jaroslava Haníková ◽  
Juraj Kuchár ◽  
Zdeněk Trávníček ◽  
Juraj Černák
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Title Compound ◽  
Basal Plane ◽  
Crystal Packing ◽  
Coordination Geometry ◽  
Apical Position

The title compound, [Cu2(OH)2(C6H16N2)2(H2O)](BF4)2, consists of dinuclear centrosymmetric [Cu2(OH)2(tmen)2(H2O)]2+ complex cations (tmen = N,N,N′,N′-tetramethylethane-1,2-diamine) and tetrafluoridoborate anions. In the cation, the CuII atom shows a slightly distorted square-pyramidal coordination geometry provided by a pair of μ-OH− anions and by the N atoms of a chelate tmen ligand in the basal plane. The apical position is statistically occupied by the O atom of a half-occupancy water molecule. The F atoms of the anion are disordered over three sets of sites with occupancies of 0.598 (9):0.269 (6):0.134 (8). The crystal packing is governed by ionic forces as well as by O—H...F hydrogen bonds.

Azido{1-[(2-diethylaminoethylimino)methyl]naphthalato}copper(II)

2006 ◽  
Vol 62 (4) ◽  
pp. m849-m850 ◽  
Author(s):  
Xiao-Yang Qiu
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Coordination Geometry ◽  
Azide Anion ◽  
Square Planar

The title compound, [Cu(C17H21N2O)(N3)], is a mononuclear copper(II) complex. The central CuII ion is four-coordinated by one O and two N atoms of the Schiff base ligand, and by one N atom of an azide anion, forming a distorted square-planar coordination geometry.

Azido{2-[(tri-2-pyridylmethyl)iminomethyl]phenolato}nickel(II)

2007 ◽  
Vol 63 (11) ◽  
pp. m2812-m2812 ◽  
Author(s):  
Lai-Jin Tian ◽  
Hong-Jun Yang ◽  
Zhong-Hai Ni
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Sodium Azide ◽  
Title Compound ◽  
Methanol Solution ◽  
The Other ◽  
Planar Geometry ◽  
Square Planar ◽  
Azide Ligand

The title compound, [Ni(C23H17N4O)(N3)], was obtained by the reaction of the Schiff base ligand 2-[(tri-2-pyridylmethyl)iminomethyl]phenol with sodium azide and nickel(II) perchlorate in methanol solution. The NiII atom is four-coordinated by the phenolate O, the imine N and a pyridine N atom of the Schiff base ligand, and by the terminal N atom of an azide ligand, forming a square-planar geometry. The other two pyridyl rings are oriented at an angle of 72.29 (11)° to each other.

{6,6′-Dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II) chloroform solvate

2006 ◽  
Vol 62 (5) ◽  
pp. m948-m949 ◽  
Author(s):  
Yu-Ye Yu
Keyword(s):  
Schiff Base ◽  
Solid State ◽  
Schiff Base Ligand ◽  
Solid State Reaction ◽  
Title Compound ◽  
Coordination Geometry ◽  
Square Planar ◽  
Salen Ligand

The title compound, [Ni(C18H18N2O4)]·CHCl3, has been synthesized by the solid-state reaction of Ni(OAc)2·4H2O and the Schiff base ligand N,N′-ethylene-bis(3-methoxysalicylaldehyde) [abbreviated as H2(3-MeO-salen)]. The Ni atom adopts a slightly deformed square-planar coordination geometry in which the 3-MeO-salen ligand acts as a cis-N2O2 donor.

scholarly journals {4,4′,6,6′-Tetrabromo-2,2′-[(2,2-dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato}copper(II)

2012 ◽  
Vol 68 (4) ◽  
pp. m392-m392
Author(s):  
Hadi Kargar ◽  
Reza Kia ◽  
Mahbubeh Haghshenas ◽  
Muhammad Nawaz Tahir
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Dihedral Angle ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Rotation Axis ◽  
Centroid Distance ◽  
Square Planar ◽  
Benzene Rings

In the title compound, [Cu(C19H16Br4N2O2)], the CuIIion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuIIion is distorted square-planar, which is defined by the N2O2donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an intermolecular π–π interaction [centroid–centroid distance = 3.8891 (18) Å].

scholarly journals A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ2 S,S′]zinc(II)]-μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3 S,S′:N] 4-methylpyridine hemisolvate]

2017 ◽  
Vol 73 (8) ◽  
pp. 1162-1166 ◽  
Author(s):  
Pavel Poplaukhin ◽  
Hadi D. Arman ◽  
Edward R. T. Tiekink
Keyword(s):  
Coordination Polymer ◽  
Title Compound ◽  
Solvent Molecule ◽  
Three Dimensional ◽  
The Other ◽  
Coordination Geometry ◽  
Asymmetric Unit ◽  
Apical Position ◽  
One Dimensional ◽  
Dithiocarbamate Ligand

The title compound, {[Zn(C9H11N2S2)2]·0.5C6H7N} n , comprises two independent, but chemically similar, Zn[S2CN(Et)CH2py]2 residues and a 4-methylpyridine solvent molecule in the asymmetric unit. The Zn-containing units are connected into a one-dimensional coordination polymer (zigzag topology) propagating in the [010] direction, with one dithiocarbamate ligand bridging in a μ2-κ3 mode, employing one pyridyl N and both dithiocarbamate S atoms, while the other is κ2-chelating. In each case, the resultant ZnNS4 coordination geometry approximates a square pyramid, with the pyridyl N atom in the apical position. In the crystal, the chains are linked into a three-dimensional architecture by methyl- and pyridyl-C—H...S, methylene-C—H...N(pyridyl) and pyridyl-C—H...π(ZnS2C) interactions. The connection between the chain and the 4-methylpyridine solvent molecule is of the type pyridyl-C—H...N(4-methylpyridine).

{1-[2-(Methylamino)ethyliminomethyl]naphthalen-2-olato}thiocyanatocopper(II)

2006 ◽  
Vol 62 (7) ◽  
pp. m1533-m1534 ◽  
Author(s):  
Han-Na Hou
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Compound ◽  
Planar Geometry ◽  
Asymmetric Unit ◽  
Thiocyanate Anion ◽  
Square Planar

The title compound, [Cu(C14H15N2O)(NCS)], is a mononuclear copper(II) complex, with two molecules in the asymmetric unit. The CuII ion is coordinated by one O and two N atoms of a Schiff base ligand, and by one N atom of a thiocyanate anion, forming a square-planar geometry.

scholarly journals {6,6′-Dimethyl-2,2′-bis[(2-oxidobenzylidene)amino]-1,1′-biphenyl-κ4O,N,N′,O′}bis(propan-2-olato-κO)titanium(IV)n-hexane hemisolvate

IUCrData ◽  
2016 ◽  
Vol 1 (9) ◽  
Author(s):  
Liang Chen ◽  
Xuebin Deng
Keyword(s):  
Schiff Base ◽  
Schiff Base Ligand ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Crystal Complex ◽  
Solvent Molecules

The mononuclear TiIVtitle complex, [Ti(C28H22N2O2)(C3H7O)2]·0.5C6H14, crystallizes as ann-hexane hemisolvate. The TiIVatom is coordinated by a dianionic tetradentate biphenyl Schiff base ligand and two O atoms of two propan-2-olate anions in a distorted TiN2O4octahedral coordination geometry, in which the two N atoms are in acisconfiguration. In the crystal, complex molecules are stacked parallel to [100], leaving space for channels parallel to [001] where the solvent molecules are located.

Dichloro{2-[(2-isopropylaminoethylimino)methyl]-4-nitrophenolato}zinc(II)

2007 ◽  
Vol 63 (3) ◽  
pp. m706-m707 ◽  
Author(s):  
Shou-Xing Wang
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Hydrogen Bonds ◽  
Schiff Base Ligand ◽  
Title Compound

In the title compound, [ZnCl2(C12H17N3O3)], a mononuclear Schiff base zinc(II) complex, the Zn atom is tetrahedrally coordinated by one imine N atom and one phenolate O-atom of the Schiff base ligand and by two terminal chloride anions. In the crystal structure, symmetry-related molecules are linked through intermolecular N—H...Cl, N—H...O and C—H...Cl hydrogen bonds, forming chains running parallel to the b axis.

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