Crystal structure of hexakis(μ2-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc
2014 ◽
Vol 70
(12)
◽
pp. 483-485
Keyword(s):
The title complex, systematic name hexakis(μ2-4-tert-butoxy-4-oxobut-2-en-2-olato)-1:2κ9O2,O4:O2;2:3κ9O2,O4:O2-trizinc, [Zn3(C8H13O3)6], synthesized fromtert-butyl acetoacetate and diethylzinc, consists of trinuclear centrosymmetric molecules of an approximateC3isymmetry. The three metal cations are arranged in a linear fashion, with the central ZnIIatom located on a centre of symmetry. All three metal cations exhibit a distorted octahedral coordination geometry. The terminal ZnIIcations are chelated by threetert-butyl acetoacetate ligands and these units are connected to the central ZnIIatom by the bridging enolate O atoms.
2007 ◽
Vol 63
(3)
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pp. m845-m846
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2014 ◽
Vol 70
(11)
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pp. m385-m386
2006 ◽
Vol 62
(5)
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pp. m1079-m1080
2016 ◽
Vol 72
(4)
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pp. 486-488
2007 ◽
Vol 63
(11)
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pp. m2654-m2654
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2006 ◽
Vol 62
(7)
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pp. m1506-m1507
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2013 ◽
Vol 69
(2)
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pp. m105-m105
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2007 ◽
Vol 63
(3)
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pp. m737-m739
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