scholarly journals Crystal Chemistry and Physics of Perovskites with Small Cations at the A Site

2014 ◽  
Vol 70 (a1) ◽  
pp. C976-C976
Author(s):  
Alexei Belik ◽  
Wei Yi ◽  
Qifeng Liang ◽  
Yoshitaka Matsushita ◽  
Masahiko Tanaka ◽  
...  

Synthesis, crystal chemistry, and physics of perovskites with small cations at the A site are an emerging field in perovskite science. Properties of ABO3 perovskites with small cations at the A site (A = Sc and In; B = transition metals) will be reported. ScBO3 and InBO3 perovskites extend the corresponding families of perovskites with A = Y, La-Lu, and Bi and exhibit larger structural distortions. As a result of large distortions, they show, in many cases, distinct structural and magnetic properties. It is manifested in B-site-ordered monoclinic structures of ScMnO3 [Inorg. Chem. 52 (2013) 9692] and `InMnO3' [Angew. Chem.: Inter. Ed. 49 (2010) 7723]; an unusual superstructure of ScRhO3 and InRhO3 [Inorg. Chem. 52 (2013) 12005]; two magnetic transitions in ScCrO3 and InCrO3 with very close transition temperatures [Chem. Mater. 24 (2012) 2197]; and antiferromagnetic ground states and multiferroic properties of Sc2NiMnO6 and In2NiMnO6 [Inorg. Chem. 52 (2013) 14108]. Features of such perovskites, such as, transition metal doping into the A site, (Sc1-xBx)BO3, will be discussed. Special attention will be given to new spin-driven multiferroics Sc2NiMnO6 and In2NiMnO6.

2021 ◽  
Vol 23 (38) ◽  
pp. 21769-21783
Author(s):  
Kumari Naveen ◽  
Tanmay Rom ◽  
Shams Sohel Islam ◽  
Manfred Reehuis ◽  
Peter Adler ◽  
...  

La-based B-site disordered double perovskites, Ca2−xLaxFeRuO6, have been investigated thoroughly. The effects of A-site substitution on the charge states and electronic and magnetic properties have been determined in a series of 3d/4d perovskites.


2004 ◽  
Vol 95 (5) ◽  
pp. 2582-2586 ◽  
Author(s):  
S. Kolesnik ◽  
B. Dabrowski ◽  
J. Mais

2010 ◽  
Vol 518 (8) ◽  
pp. 2152-2156 ◽  
Author(s):  
C.G. Jin ◽  
Y.Gao ◽  
X.M. Wu ◽  
M.L. Cui ◽  
L.J. Zhuge ◽  
...  

Author(s):  
Mohamed A. Abdelati ◽  
Ahmed A Maarouf ◽  
Mohamed Fadlallah

Monolayer MoSi2N4 (MoSiN) was successfully synthesized last year [Hong et al., Science 369, 670 (2020)]. The MoSiN monolayer exhibited semiconducting characteristics and exceptional ambient stability, calling for more studies of...


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