Crystal structure of methyl 4-(2-fluorophenyl)-6-methyl-2-sulfanylidene-1,2,3,4-tetrahydropyrimidine-5-carboxylate
2015 ◽
Vol 71
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pp. o838-o839
Keyword(s):
The Mean
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In the title compound, C13H13FN2O2S, the pyrimidine ring adopts a twist-boat conformation with the MeCNand methine-Catoms displaced by 0.0938 (6) and 0.2739 (3) Å, respectively, from the mean plane through the other four atoms of the ring. The 2-fluorobenzene ring is positioned axially and forms a dihedral angle of 89.13 (4)° with the mean plane through the pyrimidine ring. The crystal structure features N—H...O, N—H...S and C—H...O hydrogen bonds that link molecules into supramolecular chains along thebaxis. These chains are linked into a layer parallel to (10-1) by C—H...π interactions; layers stack with no specific interactions between them.
2015 ◽
Vol 71
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pp. o464-o465
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2015 ◽
Vol 71
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pp. o516-o517
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2015 ◽
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pp. o306-o307
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2015 ◽
Vol 71
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pp. o536-o537
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