Crystal structure of [1,2-bis(diphenylphosphanyl)benzene]heptacarbonyldi-μ-hydrido-(μ3-2,4,6-trimethylphenylphosphinidene)-triangulo-triruthenium
2017 ◽
Vol 73
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pp. 945-948
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The title trinuclear ruthenium cluster, [Ru3(C30H24P2)(C9H11P)(CO)7(μ-H)2], has a triangular Ru3core that is capped with a mesitylphosphinidene ligand, μ3-PMes (Mes = mesityl = 2,4,6-trimethylphenyl). The 1,2-bis(diphenylphosphanyl)benzene molecule acts as a bidentate phosphine ligandviatwo P atoms connecting to a single Ru atom. The title compound crystallizes with two independent molecules in the asymmetric unit.
2006 ◽
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2014 ◽
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2017 ◽
Vol 73
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pp. 1184-1188
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