scholarly journals (Nitrato-κO)(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)palladium(II) nitrate

IUCrData ◽  
2021 ◽  
Vol 6 (1) ◽  
Author(s):  
Kwang Ha
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Nitrate Anion ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Π Stacking ◽  
Square Planar

The title complex, [Pd(NO3)(C15H11N3)]NO3, comprises a cationic PdII complex and a nitrate anion. In the complex, the PdII cation is four-coordinated in a distorted square-planar coordination geometry defined by the three N atoms of the tridentate 2,2′:6′,2′′-terpyridine ligand and one O atom from the NO3 − anion. In the crystal, the complex molecules are stacked in columns along the a axis being connected by π–π stacking [closest inter-centroid separation between pyridyl rings = 3.878 (3) Å]. The connections between columns and anions to sustain a three-dimensional architecture are C—H...O hydrogen bonds.

A new polymorph of (dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxo-5,8,14,17-tetraazadibenzo[a,g]cyclotetradecine-13,18-dicarboxylato-κ4 N)nickel(II)

2006 ◽  
Vol 62 (4) ◽  
pp. m870-m872
Author(s):  
Chang-Qing Li ◽  
Li-Na Zhu ◽  
Xiao-Zeng Li ◽  
Rong Li
Keyword(s):  
Hydrogen Bonds ◽  
Macrocyclic Ligand ◽  
Three Dimensional ◽  
Title Complex ◽  
Planar Geometry ◽  
Supramolecular Network ◽  
Stacking Interactions ◽  
Complex Molecules ◽  
Π Stacking ◽  
Square Planar

A new polymorph of the title complex, [Ni(C22H18N4O6)], has been synthesized and structurally characterized. Ni(II) is coordinated by the four nitrogen donors of the macrocyclic ligand with a distorted square-planar geometry. C—H...O hydrogen bonds and π...π stacking interactions link the complex molecules, forming an infinite three-dimensional supramolecular network.

scholarly journals catena-Poly[[(nitrato-κ2O,O′)silver(I)]-μ3-4-pyridone-κ3O:O:O]

2009 ◽  
Vol 65 (6) ◽  
pp. m685-m686
Author(s):  
Xian-Ge Wu ◽  
Jun-Xia Xiao ◽  
Liang Qin
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Infinite Chain ◽  
Nitrate Anion ◽  
Stacking Interactions ◽  
Coordination Geometry ◽  
Π Stacking ◽  
Dimensional Network ◽  
Centroid Distance

In the title complex, [Ag(NO3)(C5H5NO)]n, the AgIatom is coordinated by two O atoms from two different 4-pyridone ligands and two O atoms from one nitrate anion, displaying a nearly planar coordination geometry. The O atoms of two 4-pyridone ligands bridge two symmetrically related AgNO3units, forming a dimer, with an Ag...Ag separation of 3.680 (2) Å. Neighbouring dimers are linked into an infinite chain through weak Ag...O interactions [2.765 (2) Å], Ag...Ag interactions [3.1511 (4) Å] and π–π stacking interactions [centroid–centroid distance = 3.623 (4) Å]. N—H...O and C—H...O hydrogen bonds assemble these chains into a three-dimensional network.

scholarly journals [1,4-Bis(diphenylphosphanyl)butane-κ2P,P′]dibromidopalladium(II)

2014 ◽  
Vol 70 (2) ◽  
pp. m41-m41
Author(s):  
Kwang Ha ◽  
Yo Soon Song
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Dihedral Angles ◽  
Maximum Deviation ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Centroid Distance ◽  
Square Planar ◽  
Phenyl Rings

In the title complex, [PdBr2(C28H28P2)], the PdIIion has a distortedcis-Br2P2square-planar coordination geometry defined by two P atoms from the chelating 1,4-bis(diphenylphosphanyl)butane ligand and two Br−anions. The four phenyl rings are inclined to the least-squares plane of the PdBr2P2unit [maximum deviation = 0.1294 (7) Å], making dihedral angles of 66.3 (2), 87.2 (2), 68.8 (2) and 86.8 (2)°. The butylene chain is in agaucheconformation, with a C—C—C—C torsion angle of 57.0 (8)°. Intermolecular C—H...Br hydrogen bonds link the complex molecules into supramolecular layers in theabplane. Weak π–π interactions, both intra- and intermolecular [shortest inter-centroid distance = 4.598 (5) Å], are also noted in the three-dimensional architecture.

scholarly journals Bis[5-(pyridin-2-yl-κN)tetrazolido-κN1]copper(II)

2014 ◽  
Vol 70 (3) ◽  
pp. m79-m79 ◽  
Author(s):  
Jian-Quan Li ◽  
Dan Mu ◽  
Meng-Bao Fan
Keyword(s):  
Title Complex ◽  
Stacking Interactions ◽  
Coordination Geometry ◽  
Inversion Center ◽  
Complex Molecules ◽  
Π Stacking ◽  
Square Planar

In the title complex, [Cu(C6H4N5)2], the CuIIion lies on an inversion center and is coordinated by two chelating 5-(pyridin-2-yl)tetrazolide ligands in a slightly distorted square-planar coordination geometry. In the crystal, π–π stacking interactions, with centroid–centroid distances in the range 3.4301 (14)–3.4387 (13) Å, link the complex molecules along [101].

scholarly journals Crystal structure of (2-amino-7-methyl-4-oxidopteridine-6-carboxylato-κ3O4,N5,O6)aqua(1,10-phenanthroline-κ2N,N′)zinc trihydrate

2015 ◽  
Vol 71 (9) ◽  
pp. m162-m163
Author(s):  
Siddhartha S. Baisya ◽  
Baidyanath Ghosh ◽  
Parag S. Roy
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Carboxylate Ligand ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Complex Molecules ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

In the title compound, [Zn(C8H5N5O3)(C12H8N2)(H2O)]·3H2O, a tridentate 2-amino-7-methyl-4-oxidopteridine-6-carboxylate ligand, a bidentate ancillary 1,10-phenanthroline (phen) ligand and a water molecule complete a distorted octahedral coordination geometry around the ZnIIatom. The pterin ligand forms two chelate rings. The phen and pterin ring systems are nearly perpendicular [dihedral angle = 85.16 (5)°]. Classical N—H...O, O—H...N and O—H...O hydrogen bonds and weak C—H...O hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional network. π–π stacking contacts are observed as well, with centroid-to-centroid distances of 3.5679 (14), 3.7004 (14), 3.6641 (15), 3.6974 (13) and 3.3412 (12) Å.

scholarly journals (2,2′-Bipyridine-κ2 N,N′)(pyridine-2,6-dicarboxylato-κ2 N,O)palladium(II) monohydrate

IUCrData ◽  
2019 ◽  
Vol 4 (12) ◽  
Author(s):  
Kwang Ha
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Title Compound ◽  
Coordination Geometry ◽  
Intermolecular Hydrogen Bonds ◽  
Complex Molecules ◽  
Solvent Water Molecule ◽  
Solvent Water ◽  
Square Planar ◽  
Bipyridine Ligand

In the title compound, [Pd(C7H3NO4)(C10H8N2)]·H2O, the PdII cation is four-coordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,2′-bipyridine ligand, one O atom and one N atom from the pyridine-2,6-dicarboxylate anion. The complex and solvent water molecule are linked by intermolecular hydrogen bonds. In the crystal, the complex molecules are stacked in columns along the a axis.

scholarly journals Bis(μ2-4-nitrophenolato)bis(4-nitrophenolato)di-μ3-oxido-octaphenyltetratin chloroform sesquisolvate [+ solvate]: a tetranuclear stannoxane

IUCrData ◽  
2019 ◽  
Vol 4 (8) ◽  
Author(s):  
Patrick Butler
Keyword(s):  
Hydrogen Bonds ◽  
Electron Density ◽  
Three Dimensional ◽  
The Other ◽  
Dimensional Structure ◽  
Coordination Geometry ◽  
Asymmetric Unit ◽  
Acta Cryst ◽  
Complex Molecules ◽  
Three Dimensional Structure

The title tetranuclear stannoxane, [Sn4(C6H5)8(C6H4NO3)4O2]·1.5CHCl3·solvent, crystallized with two independent complex molecules, A and B, in the asymmetric unit together with 1.5 molecules of chloroform. There is also a region of disordered electron density, which was corrected for using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9–18]. The oxo-tin core of each complex is in a planar `ladder' arrangement and each Sn atom is fivefold SnO3C2 coordinated, with one tin centre having an almost perfect square-pyramidal coordination geometry, while the other three Sn centres have distorted shapes. In the crystal, the complex molecules are arranged in layers, composed of A or B complexes, lying parallel to the bc plane. The complex molecules are linked by a number of C—H...O hydrogen bonds within the layers and between the layers, forming a supramolecular three-dimensional structure.

scholarly journals Crystal structure of tetraaquabis(8-chloro-9,10-dioxo-9,10-dihydroanthracene-1-carboxylato-κO1)cobalt(II) dihydrate

2014 ◽  
Vol 70 (10) ◽  
pp. m357-m358
Author(s):  
Wen-Juan Cai ◽  
Bo Liu ◽  
Feng-Yi Liu ◽  
Jun-Feng Kou
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Supramolecular Structure ◽  
Three Dimensional ◽  
Title Complex ◽  
Organic Ligands ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Π Interactions ◽  
Carboxylate Anions

In the title complex, [Co(C15H6ClO4)2(H2O)4]·2H2O, the CoIIion is bound by two carboxylate O atoms of two 5-chloro-9,10-anthraquinone-1-carboxylate anions and four water O atoms in atransconformation, forming an irregular octahedral coordination geometry. This arrangement is stabilized by intramolecular O—H...O hydrogen bonds between water and carboxylate. Further O—H...O hydrogen bonds between coordinating and non-coordinating water and carboxylate produce layers of molecules that extend parallel to (001). The organic ligands project above and below the plane. Those ligands of adjacent planes are interdigitated and there are π–π interactions between them with centroid–centroid distances of 3.552 (2) and 3.767 (2) Å that generate a three-dimensional supramolecular structure.

scholarly journals Poly[(μ3-3,5-dinitrobenzoato-κ3O1:O1′:O3)(μ2-hydroxido-κ2O:O)copper(II)]

2014 ◽  
Vol 70 (3) ◽  
pp. m112-m113 ◽  
Author(s):  
B. Sinha ◽  
G. C. Dey ◽  
B. Sarkar ◽  
A. Roy ◽  
Seik Weng Ng ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Title Complex ◽  
Axial Position ◽  
Coordination Geometry ◽  
Carboxylate Ligands ◽  
The Stability

The title complex, [Cu{μ3-O2CC6H3(NO2)2-3,5}(μ-OH)]n, features zigzag chains in which successive pairs of CuIIatoms are connected by OH bridges and bidentate carboxylate ligands, leading to six-membered Cu(O)(OCO)Cu rings. The zigzag chains are connected into a three-dimensional architecture by Cu—O(nitro) bonds. The coordination geometry of the CuIIatom is square-pyramidal, with the axial position occupied by the nitro O atom, which forms the longer Cu—O bond. Bifurcated hydroxy–nitro O—H...O hydrogen bonds contribute to the stability of the crystal structure.

N-(4-Nitrobenzyl)quinolinium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)palladium(III) acetone solvate

2006 ◽  
Vol 62 (5) ◽  
pp. m1002-m1003 ◽  
Author(s):  
Shuang-Quan Zang ◽  
Yang Su ◽  
Ruo-Jie Tao
Keyword(s):  
Hydrogen Bonds ◽  
Network Structure ◽  
Three Dimensional ◽  
Ion Pair ◽  
Supramolecular Network ◽  
Coordination Geometry ◽  
Compound C ◽  
Square Planar

In the title ion-pair compound, (C16H13N2O2)[Pd(C3S5)2]·C3H6O, the PdIII atom exhibits square-planar coordination geometry involving four S atoms of two 2-thioxo-1,3-dithiole-4,5-dithiolate (dmit) ligands. Some weak S...S interactions and hydrogen bonds are found, resulting in a three-dimensional supramolecular network structure.

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