In this chapter hybrid approach to development of intelligent systems is applied to ubiquitous computing systems, in particular, to smart environment. Different classifications of Hybrid Intelligent Systems (HIS) are looking and two examples of hybrid approach for smart environment are suggested: framework based on expert system and neural network for programming of behavior of smart objects and paradigm of context-based programming-learning of behavior of intelligent agent. Besides this chapter offers an attempt to systematize concepts for development of HIS as any introduction to methodology for development of HIS is suggested. The author hopes that this chapter will be useful for researchers and developers to better understand challenges in development of ambient intelligence and possible ways to overcome them.