Structural characterization of a mixed-ligand complex of copper(II) with 1,10-phenanthroline and the m-aminobenzoate ion

2016 ◽  
Vol 57 (5) ◽  
pp. 991-996 ◽  
Author(s):  
S. S. Batool ◽  
S. R. Gilani ◽  
M. N. Tahir ◽  
W. T. A. Harrison
Keyword(s):  
Structural Characterization ◽  
Mixed Ligand Complex ◽  
Mixed Ligand ◽  
Ligand Complex

scholarly journals Electrochemical Characterization of Biochemically Active Cu(II) Mixed Ligand Complex with Histidine and Cysteine

2016 ◽  
Vol 29 (2) ◽  
pp. 392-397 ◽  
Author(s):  
Marina Mlakar ◽  
Sonja Pavković ◽  
Lidija-Marija Tumir ◽  
Petra Vukosav ◽  
Blaženka Gašparović
Keyword(s):  
Mixed Ligand Complex ◽  
Mixed Ligand ◽  
Electrochemical Characterization ◽  
Ligand Complex

Synthesis and Structural Characterization of the Mixed Ligand Complex [Cu(Hml)2(Phen)] · 2 H2O (H2ml = 2-Methyllactic Acid)

2003 ◽  
Vol 58 (1) ◽  
pp. 151-154 ◽  
Author(s):  
Rosa Carballo ◽  
Berta Covelo ◽  
Ezequiel M. Vázquez-Lópeza ◽  
Alfonso Castiñeiras ◽  
Juan Niclós
Keyword(s):  
Magnetic Measurements ◽  
Mixed Ligand Complex ◽  
Three Dimensional ◽  
Mixed Ligand ◽  
Water Molecules ◽  
Ligand Complex ◽  
X Ray ◽  
Dimensional Network ◽  
Distorted Octahedral

Abstract A new mixed-ligand complex of copper(II) with 1,10-phenanthroline and 2-methyllactate was prepared. [Cu(HmL)2(phen)] ·2H2O (where HmL = monodeprotonated 2-methyllactic acid) was characterized by elemental analysis, IR, electronic and EPR spectroscopy, magnetic measurements at room temperature, thermogravimetric analysis and X-ray diffractometry. The copper atom is in a tetragonally distorted octahedral environment and the 2-methyllactato ligand is bidentately chelating. The presence of lattice water molecules mediates the formation of a three-dimensional network.

Quantum Mechanical Characterization of Mixed-Ligand Complex of Co(II) Dimethylglyoxime

2014 ◽  
Vol 6 (1) ◽  
pp. 13-21
Author(s):  
I.A. Adejoro ◽  
O.O. Adeboye ◽  
B. Akintoye ◽  
O.F. Akinyele
Keyword(s):  
Mechanical Characterization ◽  
Mixed Ligand Complex ◽  
Mixed Ligand ◽  
Quantum Mechanical ◽  
Ligand Complex

Synthesis, Crystal Structure, Characterization of a Pb(II) Mixed-Ligand Tetrazolate Complex

2011 ◽  
Vol 239-242 ◽  
pp. 2566-2572
Author(s):  
Ji Guang Tang ◽  
Xiang Rong Liu ◽  
Biao Su ◽  
Jun Deng ◽  
Yong Ping Wu
Keyword(s):  
Mixed Ligand Complex ◽  
Mixed Ligand ◽  
Structure Characterization ◽  
Monoclinic Space Group ◽  
Ligand Complex ◽  
Single Crystal Diffraction ◽  
Pyramidal Geometry ◽  
Square Pyramidal Geometry ◽  
Thermal Stability Of

A homometallic mixed-ligand complex Pb(BTA)(phen)·H2O was synthesized by taking hydrated N,N′-bis(1H-tetrazolyl)amine (H2BTA·H2O), 1,10-phenanthroline (phen) and PbCl2as starting materials during this work. The complex was characterized by elemental analysis, IR, UV-Vis, FS and X-ray single-crystal diffraction. The results reveal that the coordination number of the Pb ion is four and the geometry can be regarded as a square-pyramidal geometry, with two N atoms of BTA2-and two N atoms of phen at the base. Crystal data for it, C14H11N11OPb, monoclinic, space groupC2/c,a= 9.420(2) Å,b= 22.943(6) Å,c= 15.286(4) Å,α= 90.000°,β= 105.760(4)°,γ= 90.000°,V= 3179.6(14) Å3,Z= 8, finalRindices [I> 2σ(I)],R1= 0.0241, wR2= 0.0471. The thermal stability of the complex was investigated by thermogravimetric analysis. The TG profile indicates that Pb(BTA)(phen) is thermally stable up to the temperature of 588.9 K.

Synthesis and characterization of a mixed ligand complex of copper(I) with 2,9-dimethyl-1,10-phenanthroline and cyanide

1988 ◽  
Vol 149 (1) ◽  
pp. 57-62 ◽  
Author(s):  
Tetsuya Ogura ◽  
Ely Shemesh ◽  
Nelson Scott ◽  
Gloria J. Pyrka ◽  
Quintus Fernando
Keyword(s):  
Mixed Ligand Complex ◽  
Mixed Ligand ◽  
Synthesis And Characterization ◽  
Ligand Complex
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