Synthesis of 3-Chloro-3-(trimethylsilyl)prop-2-enoic Acid Amides and Hydrazides from 3-(Trimethylsilyl)propynoic Acid

2021 ◽  
Vol 57 (4) ◽  
pp. 565-574
Author(s):  
M. V. Andreev ◽  
M. M. Demina ◽  
A. S. Medvedeva ◽  
L. P. Safronova ◽  
A. I. Albanov ◽  
...  
Keyword(s):  



2011 ◽  
Vol 11 (1) ◽  
pp. 19-22 ◽  
Author(s):  
Se-Jeong Park ◽  
Seung Hee Kang ◽  
Young Ku Kang ◽  
Yong-Bin Eom ◽  
Kwang Oh Koh ◽  
...  


2011 ◽  
Vol 77 (8) ◽  
pp. 2634-2639 ◽  
Author(s):  
Zhenming Zhou ◽  
Qingxiang Meng ◽  
Zhongtang Yu

ABSTRACTThe objective of this study was to systematically evaluate and compare the effects of select antimethanogen compounds on methane production, feed digestion and fermentation, and populations of ruminal bacteria and methanogens usingin vitrocultures. Seven compounds, including 2-bromoethanesulphonate (BES), propynoic acid (PA), nitroethane (NE), ethyltrans-2-butenoate (ETB), 2-nitroethanol (2NEOH), sodium nitrate (SN), and ethyl-2-butynote (EB), were tested at a final concentration of 12 mM. Ground alfalfa hay was included as the only substrate to simulate daily forage intake. Compared to no-inhibitor controls, PA, 2NEOH, and SN greatly reduced the production of methane (70 to 99%), volatile fatty acids (VFAs; 46 to 66%), acetate (30 to 60%), and propionate (79 to 82%), with 2NEOH reducing the most. EB reduced methane production by 23% without a significant effect on total VFAs, acetate, or propionate. BES significantly reduced the propionate concentration but not the production of methane, total VFAs, or acetate. ETB or NE had no significant effect on any of the above-mentioned measurements. Specific quantitative-PCR (qPCR) assays showed that none of the inhibitors significantly affected total bacterial populations but that they did reduce theFibrobacter succinogenespopulation. SN reduced theRuminococcus albuspopulation, while PA and 2NEOH increased the populations of bothR. albusandRuminococcus flavefaciens. Archaeon-specific PCR-denaturing gradient gel electrophoresis (DGGE) showed that all the inhibitors affected the methanogen population structure, while archaeon-specific qPCR revealed a significant decrease in methanogen population in all treatments. These results showed that EB, ETB, NE, and BES can effectively reduce the total population of methanogens but that they reduce methane production to a lesser extent. The results may guide futureinvivostudies to develop effective mitigation of methane emission from ruminants.



1957 ◽  
Vol 35 (8) ◽  
pp. 757-760 ◽  
Author(s):  
K. K. Carroll

The malonic ester synthesis of nervonic acid (tetracos-15-enoic acid) has been modified so that the product consists of pure cis rather than a mixture of cis and trans isomers. The modified synthesis has been used for the preparation of C14-labelled erucic and nervonic acids.



1986 ◽  
Vol 22 (5) ◽  
pp. 595-597 ◽  
Author(s):  
V. N. Odinokov ◽  
G. Yu. Ishmuratov ◽  
I. M. Ladenkova ◽  
G. A. Tolstikov
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1989 ◽  
Vol 32 (5) ◽  
pp. 974-984 ◽  
Author(s):  
Steven E. Hall ◽  
Wen Ching Han ◽  
Don N. Harris ◽  
Anders Hedberg ◽  
Martin L. Ogletree
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2018 ◽  
Vol 54 (6) ◽  
pp. 1149-1151 ◽  
Author(s):  
M. P. Yakovleva ◽  
G. R. Mingaleeva ◽  
V. A. Vydrina ◽  
A. A. Kravchenko ◽  
G. Yu. Ishmuratov
Keyword(s):  




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