The effect of the disperse composition of a titanium catalyst on the kinetic heterogeneity of isoprene polymerization centers

2013 ◽  
Vol 55 (9-10) ◽  
pp. 497-507 ◽  
Author(s):  
V. Z. Mingaleev ◽  
E. M. Zakharova ◽  
V. P. Zakharov
Keyword(s):  
Titanium Catalyst ◽  
Disperse Composition ◽  
Kinetic Heterogeneity ◽  
Isoprene Polymerization

Enhancement of the activity of the titanium catalyst for isoprene polymerization by improving the step of active site formation

2011 ◽  
Vol 84 (8) ◽  
pp. 1434-1437 ◽  
Author(s):  
Yu. V. Morozov ◽  
I. Sh. Nasyrov ◽  
V. P. Zakharov ◽  
V. Z. Mingaleev ◽  
Yu. B. Monakov
Keyword(s):  
Active Site ◽  
Site Formation ◽  
Titanium Catalyst ◽  
Isoprene Polymerization

Bis(tetramethylaluminate) Lanthanide Complexes Supported by Amidinate Ligands with a Pendant Ph2P═X (X = O, S) Group: Application in Isoprene Polymerization

2021 ◽  
Author(s):  
Olesya A. Basalova ◽  
Aleksei O. Tolpygin ◽  
Tatyana A. Kovylina ◽  
Anton V. Cherkasov ◽  
Georgy K. Fukin ◽  
...  
Keyword(s):  
Lanthanide Complexes ◽  
Isoprene Polymerization

One-pot synthesis of cobalt complexes with 2,6-bis(arylimino)phenoxyl/phenthioxyl ligands and catalysis on isoprene polymerization

2021 ◽  
Vol 50 (15) ◽  
pp. 5218-5225
Author(s):  
Xue-Meng Chen ◽  
Li-Cheng Huang ◽  
Wei Gao
Keyword(s):  
Mixed Valence ◽  
Cobalt Complexes ◽  
One Pot ◽  
One Pot Synthesis ◽  
Isoprene Polymerization

Several cobalt complexes supported by 2,6-bis(arylimino)phenoxyl/phenthioxyl ligands κ2N,X-Ar[NXN]CoCl(THF) were synthesized by direct oxygen(sulfur) insertion into the C–Co bond of the mixed-valence cobalt complexes {κ2C,N,η6-Ar[NCN]Co-κN-CoCl(μ-Cl)}2.

Carbon bridged triphenolate lanthanide complexes: synthesis, characterization, DFT studies and catalytic activities for isoprene polymerization

2015 ◽  
Vol 44 (24) ◽  
pp. 11182-11190 ◽  
Author(s):  
Min Zhang ◽  
Zhenhua Liang ◽  
Jun Ling ◽  
Xufeng Ni ◽  
Zhiquan Shen
Keyword(s):  
Lanthanide Complexes ◽  
Theoretical Calculations ◽  
Dft Studies ◽  
Catalytic Activities ◽  
Isoprene Polymerization

Lanthanide complexes supported by carbon bridged triphenolate ligands were synthesized and theoretical calculations were carried out on a Lu complex.

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