Molar excess enthalpies, volumes, and Gibbs free energies of methanol – isomeric butanol systems at 25 °C
1970 ◽
Vol 48
(16)
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pp. 2457-2465
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Keyword(s):
The vapor–liquid equilibria of the 4 binary systems formed by mixing methanol with n-butanol, isobutanol, sec-butanol, and tert-butanol were investigated at 25 °C in a dynamic still with circulation. The results were used to calculate the molar excess Gibbs free energies. For the three systems containing isobutanol, sec-butanol, or tert-butanol, molar excess enthalpies and volumes were also determined (mainly at 25 °C) by direct calorimetric and dilatometric techniques. The behavior of the excess properties is discussed with reference to differences in the hydrogen bonding and in the shapes of the component molecules.
1971 ◽
Vol 49
(15)
◽
pp. 2481-2489
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2003 ◽
Vol 212
(1-2)
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pp. 221-231
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Keyword(s):
2007 ◽
Vol 258
(2)
◽
pp. 168-178
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2004 ◽
Vol 49
(6)
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pp. 1602-1612
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Keyword(s):
2010 ◽
Vol 291
(1)
◽
pp. 18-31
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2004 ◽
Vol 21
(4)
◽
pp. 858-866
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Keyword(s):
Keyword(s):
2003 ◽
Vol 48
(5)
◽
pp. 1183-1190
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Keyword(s):