Electronic Spectrum of Cobalt(II) in Sulfates. Part III. Equilibrium Studies in Li2SO4–DMSO Solution and in NaHSO4−KHSO4 Melt
Keyword(s):
The results of a study of the electronic absorption spectrum of cobalt(II) in Li2SO4–DMSO solution, an equimolar NaHSO4–KHSO4 melt, a eutectic melt of Li2SO4–Na2SO4–K2SO4, single salt melts of Li2SO4 and Na2SO4 and a doped single crystal of K2Zn2(SO4)3 have been combined with previous results in sulfate media; all the results can be explained in terms of a blue dodecahedral [Co(O2SO2)4]6− species, a pink octahedral [Co(OSO3)6]10− species or an equilibrium mixture of the two.
1987 ◽
Vol 37
(11)
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pp. 1296-1300
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1984 ◽
Vol 106
(2)
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pp. 287-292
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1986 ◽
Vol 5
(2-3)
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pp. 57-70
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Keyword(s):
1975 ◽
Vol 37
(4)
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pp. 903-906
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1974 ◽
Vol 26
(4)
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pp. 601-603
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1970 ◽
Vol 52
(10)
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pp. 5159-5163
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