Standard enthalpies of formation of tris(β-diketonate)manganese(III) complexes: the mean (Mn—O) bond-dissociation enthalpies
Keyword(s):
The Mean
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The standard molar enthalpies of formation of the crystalline complexes of manganese(III) with 1-phenyl-1,3-butanedione (HBZAC) and 2,2,6,6-tetramethyl-3,5-heptanedione (HDPM) were determined, at 298.15 K, by solution–reaction calorimetry:[Formula: see text]The mean molar bond-dissociation enthalpies, [Formula: see text], were derived as 163 ± 10 kJ mol−1 and 170 ± 10 kJ mol−1, respectively.
1984 ◽
Vol 16
(2)
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pp. 137-144
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1983 ◽
pp. 2657-2659
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1988 ◽
Vol 20
(3)
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pp. 359-361
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1995 ◽
Vol 27
(12)
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pp. 1365-1372
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1992 ◽
Vol 24
(6)
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pp. 595-599
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1992 ◽
Vol 24
(6)
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pp. 585-594
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1987 ◽
Vol 19
(6)
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pp. 645-652
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