Application of Ru(II)porphyrin complexes as epoxidation catalyst of olefins
2007 ◽
Vol 11
(02)
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pp. 95-99
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Keyword(s):
Two complexes of ruthenium(II) carbonyl tetraphenyl- and tetramesytilporphyrins were used as catalysts for epoxidation of olefins using metachloroperbenzoic acid and iodosylbenzene, as oxidants. Better results were obtained with the ( TPP ) RuCO catalyst in the presence of metachloroperbenzoic acid; however, iodosylbenzene showed higher yields than metachloroperbenzoic acid for some aromatic olefins. The effect of imidazole axial base was also investigated. Two different pathways are proposed based on these two oxygen atom transfer agents.
1985 ◽
Vol 107
(7)
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pp. 2000-2005
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Keyword(s):
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1985 ◽
Vol 107
(14)
◽
pp. 4343-4345
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Keyword(s):
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1987 ◽
Vol 52
(20)
◽
pp. 4545-4553
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1984 ◽
Vol 81
(10)
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pp. 3245-3248
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Keyword(s):
2011 ◽
Vol 1
(2)
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pp. 140-145
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Keyword(s):