First Electrochemical Studies on "CAP - PAIR" Effect for BI(III) Ion Electroreduction in the Presence of 2-Thiocytosine on Novel Cyclically Renewable Liquid Silver Amalgam Film Electrode (R-AGLAFE)

Author(s):  
Agnieszka Nosal-Wiercińska ◽  
Marlena Martyna ◽  
Mariusz Grochowski ◽  
Boguslaw Bas
Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3972
Author(s):  
Agnieszka Nosal-Wiercińska ◽  
Marlena Martyna ◽  
Valentin Mirčeski ◽  
Sławomira Skrzypek

The catalytic influence of methionine (Mt) on the electroreduction of Bi(III) ions on the novel, cyclically renewable liquid silver amalgam film electrode (R–AgLAFE) in a non-complexing electrolyte solution was examined. The presence of methionine leads to a multistep reaction mechanism, where the transfer of the first electron is the rate limiting step, which is the subject of catalytic augmentation. The catalytic activity of methionine is a consequence of its ability to remove water molecules from the bismuth ion coordination sphere, as well as to form active complexes on the electrode surface, facilitating the electron transfer process.


2014 ◽  
Vol 132 ◽  
pp. 49-57 ◽  
Author(s):  
Olga Vajdle ◽  
Jasmina Zbiljić ◽  
Bojan Tasić ◽  
Danica Jović ◽  
Valéria Guzsvány ◽  
...  

2013 ◽  
Vol 699 ◽  
pp. 33-39 ◽  
Author(s):  
Valéria Guzsvány ◽  
Jelena Petrović ◽  
Jugoslav Krstić ◽  
Zsigmond Papp ◽  
Maria Putek ◽  
...  

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