ELECTRON SPIN RESONANCE STUDY OF SPIN PROBES IN FROZEN AQUEOUS SOLUTIONS. II. ICE STRUCTURE BREAKING EFFECTS OF ALKALI HYDROXIDES

1977 ◽  
Vol 6 (9) ◽  
pp. 1051-1052
Author(s):  
Eiji Sato ◽  
Shogo Uematsu ◽  
Yukio Akahori
Keyword(s):  
Electron Spin Resonance ◽  
Aqueous Solutions ◽  
Electron Spin ◽  
Electron Spin Resonance Study ◽  
Spin Probes ◽  
Spin Resonance ◽  
Alkali Hydroxides ◽  
Structure Breaking ◽  
Spin Resonance Study

Electron spin resonance study of spin-trapped azide radicals in aqueous solutions

1980 ◽  
Vol 58 (15) ◽  
pp. 1592-1595 ◽  
Author(s):  
Walter Kremers ◽  
Ajit Singh
Keyword(s):  
Electron Spin Resonance ◽  
Aqueous Solutions ◽  
Hydroxyl Radicals ◽  
Electron Spin ◽  
Sodium Azide ◽  
Electron Spin Resonance Study ◽  
Spin Traps ◽  
Spin Resonance ◽  
Hyperfine Splittings ◽  
Spin Resonance Study

Organic spin traps have been used to study the formation of azide radicals during the reaction of azide anions with hydroxyl radicals. The azide radicals have been successfully trapped with three spin traps: 5,5-dimethylpyrroline-1-oxide (DMPO), phenyl-N-tert-bulyl nitrone (PBN), and 4-pyridyl-N-tert-butyl nitrone (PyBN). The azide radicals produced from 15N sodium azide have also been trapped. The hyperfine splittings of the resulting radicals have been determined.

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