scholarly journals Asymmetric Induction Reactions. VI. Asymmetric Synthesis of a Cyclopentene Derivative by Transition Metal-Catalyzed Asymmetric Vinylcyclopropane-Cyclopentene Rearrangements with Chiral Phosphine Ligands.

1994 ◽  
Vol 42 (3) ◽  
pp. 470-474 ◽  
Author(s):  
Kunio HIROI ◽  
Yoshihisa ARINAGA ◽  
Takashi OGINO
Keyword(s):  
Transition Metal ◽  
Asymmetric Synthesis ◽  
Phosphine Ligands ◽  
Asymmetric Induction ◽  
Chiral Phosphine Ligands ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Asymmetric synthesis to chiral organosilicon compounds via transition metal-catalyzed stereoselective C-H activation and silylation

2021 ◽  
Author(s):  
Ming Zhang ◽  
Shan Gao ◽  
Juan Tang ◽  
Ling Chen ◽  
Aihua Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Asymmetric Synthesis ◽  
Organosilicon Compounds ◽  
Feature Article ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This feature article introduces the progress of transition metal-catalyzed stereoselective sp2 and sp3 C-H activation and silylation to synthesize chiral organosilicon compounds, the asymmetric C-H silylation includes intramolecular cyclizing silylation...

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