We describe a method to protect the sensitive stereochemistry of the thioamide—in analogy to the protection of the functional groups of amino acid side chains—in order to preserve the thioamide moiety during peptide elongation.<br>
Biomimetic studies using artificial system. IV. Biomimetic peptide synthesis by using multi-functionalized crown ethers as a novel enzyme model. A new concepts in mimicking of enzyme-catalyzed bond-forming reactions.
