Übergangsmetall-Schwefelylid-Komplexe, XXII [1] Zur Reaktivität von DicarbonylnitrosyI-η5-thiacyclohexadienyl-1-oxid- Chromkomplexen gegenüber Phosphor- und Schwefelyliden / Transition Metal Sulfur Ylide Complexes, XXII [1] Reactivity Studies of Dicarbonylnitrosyl-η5-thiacyclohexadienyl-1-oxide Chromium Complexes with Phosphorus and Sulfur Ylides

3a-dη5-Thiacyclohexadienyl-1-oxide chromium complexes are generated by treatment of the 1-methyl-thiabenzene-1-oxide complexes 1a-d with Li[BHEt3] and successive nitrosylation of the intermediates 2a-d. 3a-d react with Me2S(O) = CH2 or Ph3P=CH2 at a carbonyl ligand in an additon/transylidation process to yield the very sensitive products 5, 6a-d.

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ChemInform Abstract: TRANSITION METAL SULFUR YLIDE COMPLEXES. XXI. η3,Σ-SULFUR DOUBLE-YLIDE COMPLEXES BY ENDO-HYDRIDE ADDITION TO CATIONIC (THIABENZENE 1-OXIDE)CHROMIUM COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198532286 ◽

1985 ◽

Vol 16 (32) ◽

Author(s):

L. WEBER ◽

R. BOESE

Keyword(s):

Transition Metal ◽

Chromium Complexes ◽

Sulfur Ylide ◽

Ylide Complexes

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Transition-metal-substituted diphosphenes. 12. Transition-metal sulfur ylide complexes. 25. Alkylidene transfer to the P:P double bond of diphosphenyl complexes by means of the sulfur ylides (CH3)2S(O):CH2 and (c-C3H4)SPh2. X-ray structure analysis of [cyclic] (.eta.5-C5Me5)(CO)2FePC(CH2CH2)PAr (Ar = 2,4,6-tert-Bu3C6H2)

Organometallics ◽

10.1021/om00094a030 ◽

1988 ◽

Vol 7 (4) ◽

pp. 978-983 ◽

Cited By ~ 36

Author(s):

Lothar. Weber ◽

Ewald. Luecke ◽

Roland. Boese

Keyword(s):

Double Bond ◽

Transition Metal ◽

Structure Analysis ◽

Sulfur Ylides ◽

X Ray ◽

Sulfur Ylide ◽

Ylide Complexes

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Transition-metal sulfur ylide complexes. 23. Methylene transfer from sulfur ylides to transition-metal complexes: a parallel between sulfur ylides and diazomethane to organometallic chemistry

Organometallics ◽

10.1021/om00141a031 ◽

1986 ◽

Vol 5 (10) ◽

pp. 2114-2116 ◽

Cited By ~ 7

Author(s):

Lothar. Weber ◽

Ewald. Luecke

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Organometallic Chemistry ◽

Transition Metal Complexes ◽

Sulfur Ylides ◽

Sulfur Ylide ◽

Ylide Complexes

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ChemInform Abstract: TRANSITION METAL-SULFUR YLIDE COMPLEXES. PART 19. NEW η3, Σ-SULFUR DOUBLE YLIDE-CHROMIUM COMPLEXES BY ENDO-HYDRIDE ADDITION ON CATIONIC Λ6-THIABENZENE 1-OXIDE-CHROMIUM COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198345299 ◽

1983 ◽

Vol 14 (45) ◽

Author(s):

L. WEBER ◽

R. BOESE

Keyword(s):

Transition Metal ◽

Chromium Complexes ◽

Sulfur Ylide ◽

Ylide Complexes

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ChemInform Abstract: Transition-Metal-Substituted Diphosphenes. Part 12. Transition-Metal Sulfur Ylide Complexes. Part 25. Alkylidene Transfer to the P=P Double Bond of Diphosphenyl Complexes by Means of the Sulfur Ylides (CH3)2S(O)=CH2 and (c-C3H4)SPh2.

ChemInform ◽

10.1002/chin.198831266 ◽

1988 ◽

Vol 19 (31) ◽

Author(s):

L. WEBER ◽

E. LUECKE ◽

R. BOESE

Keyword(s):

Double Bond ◽

Transition Metal ◽

Sulfur Ylides ◽

Sulfur Ylide ◽

Ylide Complexes

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ChemInform Abstract: TRANSITION METAL SULFUR YLIDE COMPLEXES. XVIII. DEOXYGENATION OF ANTI-TRICARBONYL(1-METHYL-3,5-DIORGANYL-Λ6-THIABENZENE OXIDE)CHROMIUM, -MOLYBDENUM, AND -TUNGSTEN AS A NOVEL SYNTHETIC ROUTE TO Λ4-THIABENZENE COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198337284 ◽

1983 ◽

Vol 14 (37) ◽

Author(s):

L. WEBER

Keyword(s):

Transition Metal ◽

Synthetic Route ◽

Sulfur Ylide ◽

Ylide Complexes ◽

And Tungsten

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Electrochemistry of transition-metal-.pi.-complexes. 8. Oxidation of chromium, molybdenum, and tungsten sulfur ylide complexes

Organometallics ◽

10.1021/om00121a017 ◽

1985 ◽

Vol 4 (2) ◽

pp. 302-305

Author(s):

Ulrich. Koelle ◽

Tingzhen. Ding ◽

Lothar. Weber

Keyword(s):

Transition Metal ◽

Sulfur Ylide ◽

Pi Complexes ◽

Ylide Complexes ◽

And Tungsten

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ChemInform Abstract: TRANSITION METAL SULFUR YLIDE COMPLEXES. XVI. 1-METHYL-3,5-DIORGANYLTHIABENZENE 1-OXIDE COMPLEXES: SYNTHESIS AND STEREOCHEMISTRY

Chemischer Informationsdienst ◽

10.1002/chin.198329277 ◽

1983 ◽

Vol 14 (29) ◽

Author(s):

L. WEBER ◽

D. WEWERS

Keyword(s):

Transition Metal ◽

Sulfur Ylide ◽

Ylide Complexes

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ÜbergangsmetaU-Schwefelylid-Komplexe, XI [1] Struktur und Reaktivität von n5 -Thiacyclohexadienyl-1-oxid-chrom-KompIexeii / Transition Metal Sulfur Ylide Complexes, XI [1] Structure and Reactivity of n5-Thiacyclohexadienyl-1-oxide Complexes of Chromium

Zeitschrift für Naturforschung B ◽

10.1515/znb-1981-0214 ◽

1981 ◽

Vol 36 (2) ◽

pp. 198-204 ◽

Cited By ~ 3

Author(s):

Lothar Weber ◽

Dorothee Vehreschild-Yzermann ◽

Carl Krüger ◽

Gotthelf Wolmershäuser

Keyword(s):

Molecular Structure ◽

Transition Metal ◽

Crystal And Molecular Structure ◽

X Ray ◽

Sulfur Ylide ◽

Ylide Complexes

Abstract The X-ray crystal and molecular structure of tetraethylammonium-tricarbonyl-(3,5-diphenylthiacyclohexadienyl-1-oxide)chromate has been determined. This organo-metallic anion can be nitrosylated to yield neutral [n5-C5H3(C6H5)2SO](CO)2(NO)Cr. Further carbonyl displacement in this compound is achieved by treatment with pyridin or phosphanes in the presence of triethylamineoxide.

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ChemInform Abstract: TRANSITION METAL SULFUR YLIDE COMPLEXES. XV. SYNTHESIS OF 2H-THIOPYRANCHROMIUM COMPLEXES FROM TETRAETHYLAMMONIUM TRICARBONYL(η5-3,3-DIPHENYL-1-THIACYCLOHEXADIENYL 1-OXIDE)CHROMATE AND HARD ELECTROPHILES.

Chemischer Informationsdienst ◽

10.1002/chin.198319286 ◽

1983 ◽

Vol 14 (19) ◽

Author(s):

L. WEBER ◽

R. BOESE

Keyword(s):

Transition Metal ◽

Sulfur Ylide ◽

Ylide Complexes

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