scholarly journals Crystal structure of Tutton’s salts, Cs2[MII(H2O)6](SeO4)2, MII = Mg, Mn, Co, Ni, Zn

2003 ◽  
Vol 218 (4) ◽  
pp. 405-408 ◽  
Author(s):  
H. Euler ◽  
B. Barbier ◽  
A. Meents ◽  
A. Kirfel
Keyword(s):  
Crystal Structure ◽  
Tutton’S Salts

Abstract Cs2H12MgO14Se2, monoclinic, P121/a1 (No. 14), a = 9.513(1) Å, b = 13.037(1) Å, c = 6.4730(8) Å, β = 106.244(8)°, V = 770.7 Å3, Z = 2, Rgt(F) = 0.020, wRref(F2) = 0.036, T = 293 K. Cs2H12MnO14Se2, monoclinic, P121/a1 (No. 14), a = 9.591(1) Å, b = 13.141(2) Å, c = 6.5040(9) Å, β = 106.38(1)°, V = 786.5 Å3, Z = 2, Rgt(F) = 0.021, wRref(F2) = 0.043, T = 293 K. CoCs2H12O14Se2, monoclinic, P121/a1 (No. 14), a = 9.494(1)Å, b = 13.009(1) Å, c = 6.4833(8) Å, β = 106.239(9)°, V = 768.8 Å3, Z = 2, Rgt(F) = 0.016, wRref(F2) = 0.032, T = 293 K. Cs2H12NiO14Se2, monoclinic, P121/a1 (No. 14), a = 9.426(3)Å, b = 12.961(2) Å, c = 6.473(2) Å, β = 106.17(2)°, V = 759.5 Å3, Z = 2, Rgt(F) = 0.017, wRref(F2) = 0.034, T = 293 K. Cs2H12O14Se2Zn, monoclinic, P121/a1 (No. 14), a = 9.483(1) Å, b = 13.005(2) Å, c = 6.4850(8) Å, β = 106.16(1)°, V = 768.2 Å3, Z = 2, Rgt(F) = 0.019, wRref(F2) = 0.037, T = 293 K.

scholarly journals Crystal structure of Tutton’s salts, Rb2[MII(H2O)6](SO4)2, MII = Mg, Mn, Fe, Co, Ni, Zn

2000 ◽  
Vol 215 (4) ◽  
pp. 473-476 ◽  
Author(s):  
H. Euler ◽  
B. Barbier ◽  
S. Klumpp ◽  
A. Kirfel
Keyword(s):  
Crystal Structure ◽  
Tutton’S Salts

scholarly journals Crystal structure of Tutton’s salts, Rb2[MII(H2O)6](SeO4)2, MII = Mg, Co, Mn, Zn

2003 ◽  
Vol 218 (3) ◽  
pp. 265-268 ◽  
Author(s):  
H. Euler ◽  
B. Barbier ◽  
A. Meents ◽  
A. Kirfel
Keyword(s):  
Crystal Structure ◽  
Tutton’S Salts

Abstract H12MgO14Rb2Se2, monoclinic, P121/a1 (No. 14), a = 9.401(1) Å, b = 12.658(2) Å, c = 6.339(1) Å, β = 105.25(1)°, V = 727.8 Å3, Z = 2, Rgt(F) = 0.020, wRref(F2) = 0.040, T = 293 K.CoH12O14Rb2Se2, monoclinic, P121/a1 (No. 14), a = 9.363(1) Å, b = 12.618(1) Å, c = 6.3562(7) Å, β = 105.238(9)°, V = 724.5Å3, Z = 2, Rgt(F) = 0.018, wRref(F2) = 0.037, T = 293 K. H12MnO14Rb2Se2, monoclinic, P121/a1 (No. 14), a = 9.4496(8) Å, b = 12.760(1) Å, c = 6.3794(7) Å, β = 105.189(7)°, V = 742.4Å3, Z = 2, Rgt(F) = 0.025, wRref(F2) = 0.056, T = 293 K. H12O14Rb2Se2Zn, monoclinic, P121/a1 (No. 14), a = 9.352(1) Å, b = 12.626(2) Å, c = 6.360(1) Å, β = 105.195(8)°, V = 724.7 Å3, Z = 2, Rgt(F) = 0.024, wRref(F2) = 0.048, T = 293 K.

The crystal structure of Tutton's salts. V. Manganese ammonium sulfate hexahydrate

1966 ◽  
Vol 20 (6) ◽  
pp. 731-733 ◽  
Author(s):  
H. Montgomery ◽  
R. V. Chastain ◽  
E. C. Lingafelter
Keyword(s):  
Crystal Structure ◽  
Ammonium Sulfate ◽  
Tutton’S Salts

Hemi(piperazinediium) hexaaquaaluminium(III) bis(sulfate) tetrahydrate: a new double aluminium sulfate salt

2003 ◽  
Vol 59 (11) ◽  
pp. m459-m461 ◽  
Author(s):  
Thierry Bataille
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Title Compound ◽  
Structure Type ◽  
Hydrogen Bond Network ◽  
Sulfate Salt ◽  
Aluminium Sulfate ◽  
Bond Network ◽  
Tutton’S Salts

Piperazinium aluminium sulfate decahydrate, (C4H12N2)0.5[Al(H2O)6](SO4)2·4H2O, exhibits a crystal structure built from isolated [Al(H2O)6]3+, SO4 2−, C4H12N2 2+ and H2O units connected by a complex hydrogen-bond network. The title compound shows strong similarities to many double aluminium sulfates, such as alums and Tutton's salts. However, since its structure is not derived directly from that of these compounds, it is assumed to be a new structure type.

The crystal structure of Tutton's salts. III. Copper ammonium sulfate hexahydrate

1966 ◽  
Vol 20 (5) ◽  
pp. 659-662 ◽  
Author(s):  
H. Montgomery ◽  
E. C. Lingafelter
Keyword(s):  
Crystal Structure ◽  
Ammonium Sulfate ◽  
Tutton’S Salts ◽  
Copper Ammonium

The crystal structure of Tutton's salts. I. Zinc ammonium sulfate hexahydrate

1964 ◽  
Vol 17 (10) ◽  
pp. 1295-1299 ◽  
Author(s):  
H. Montgomery ◽  
E. C. Lingafelter
Keyword(s):  
Crystal Structure ◽  
Ammonium Sulfate ◽  
Tutton’S Salts
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