Rotational Invariant Expansion of the Mayerf-Function: Its Use in Calculations of Second Virial Coefficients for Molecular Fluids

1987 ◽  
Vol 155 (Part_1_2) ◽  
pp. 1-10
Author(s):  
M. Assfalg ◽  
M. D. Zeidler
1998 ◽  
Vol 102 (51) ◽  
pp. 10568-10575 ◽  
Author(s):  
Fernando del Río ◽  
J. Eloy Ramos ◽  
Ian A. McLure

2000 ◽  
Vol 65 (9) ◽  
pp. 1464-1470 ◽  
Author(s):  
Anatol Malijevský ◽  
Tomáš Hujo

The second and third virial coefficients calculated from the Bender equation of state (BEOS) are tested against experimental virial coefficient data. It is shown that the temperature dependences of the second and third virial coefficients as predicted by the BEOS are sufficiently accurate. We conclude that experimental second virial coefficients should be used to determine independently five of twenty constants of the Bender equation. This would improve the performance of the equation in a region of low-density gas, and also suppress correlations among the BEOS constants, which is even more important. The third virial coefficients cannot be used for the same purpose because of large uncertainties in their experimental values.


1971 ◽  
Vol 55 (5) ◽  
pp. 2071-2075
Author(s):  
Fouad Khoury ◽  
D. B. Robinson

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