Case Studies of Limestone-Bed Passive Systems for Manganese Removal from Acid Mine Drainage

2003 ◽  
Vol 2003 (1) ◽  
pp. 1059-1078 ◽  
Author(s):  
A. W. Rose ◽  
P. J. Shah ◽  
B. Means
2018 ◽  
Vol 156 ◽  
pp. 03046 ◽  
Author(s):  
Widyawanto Prastistho ◽  
Winarto Kurniawan ◽  
Hirofumi Hinode

The influences of mechanical milling on Indonesian Natural Bentonite (INB) characteristics and manganese (Mn) removal from acid mine drainage (AMD) were investigated. The INB characteristics were observed by scanning electron microscope (SEM), X-ray diffraction (XRD), nitrogen adsorption-desorption for specific surface area (SSA) and microporosity measurement, cation exchange capacity (CEC) and particle size distribution (PSD) analyzer. Four minutes milling with frequency 20 Hz on INB caused morphological change which showed more crumbled and destructed particle, lost the (001) peak but still retained the (100) peak that indicated delamination of montmorillonite mineral without breaking the tetrahedral-octahedral-tetrahedral (T-O-T) structure, rose the CEC from 28.49 meq/100g to 35.51 meq/100g, increase in the SSA from 60.63 m2/g to 104.88 m2/g, significant increase in microporosity which described in the t plots and decrease in the mean particle size distribution peak from 49.28 μm to 38.84 μm. The effect of contact time and effect of adsorbent dosage on Mn sorption was studied. Both unmilled and milled samples reached equilibrium at 24 hours and the pH rose from 4 to 7 in first 30 minutes. The Mn removal percentage increased significantly after milling. Using Langmuir isotherm, the maximum adsorbed metals (qmax) also increased from 0.570 to 4.219 mg/g.


2006 ◽  
Vol 2006 (2) ◽  
pp. 738-763
Author(s):  
Phoebe L. Hauff ◽  
Douglas C. Peters ◽  
David W. Coulter ◽  
Matthew A. Sares ◽  
David A. Bird ◽  
...  

2006 ◽  
Vol 14 (12-13) ◽  
pp. 1139-1145 ◽  
Author(s):  
Ata Akcil ◽  
Soner Koldas

1996 ◽  
Vol 9 (1) ◽  
pp. 23-42 ◽  
Author(s):  
B. Gazea ◽  
K. Adam ◽  
A. Kontopoulos

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Regeane M. Freitas ◽  
Thomaz A. G. Perilli ◽  
Ana Claudia Q. Ladeira

Although oxidative precipitation by potassium permanganate is a widely recognised process for manganese removal, research dealing with highly contaminated acid mine drainage (AMD) has yet to be performed. The present study investigated the efficiency of KMnO4in removing manganese from AMD effluents. Samples of AMD that originated from inactive uranium mine in Brazil were chemically characterised and treated by KMnO4at pH 3.0, 5.0, and 7.0. Analyses by Raman spectroscopy and geochemical modelling using PHREEQC code were employed to assess solid phases. Results indicated that the manganese was rapidly oxidised by KMnO4in a process enhanced at higher pH. The greatest removal, that is, 99%, occurred at pH 7.0, when treated waters presented manganese levels as low as 1.0 mg/L, the limit established by the Brazilian legislation. Birnessite (MnO2), hausmannite (Mn3O4), and manganite (MnOOH) were detected by Raman spectroscopy. These phases were consistently identified by the geochemical model, which also predicted phases containing iron, uranium, manganese, and aluminium during the correction of the pH as well as bixbyite (Mn2O3), nsutite (MnO2), pyrolusite (MnO2), and fluorite (CaF2) following the KMnO4addition.


IARJSET ◽  
2017 ◽  
Vol 4 (5) ◽  
pp. 131-137 ◽  
Author(s):  
Vikram Seervi. ◽  
Yadav H.L ◽  
Srivastav S.K ◽  
Jamal A

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