scholarly journals Synthesis and characterization of calcium hydroxyapatite (Hap) and Ti(IV)-substituted Hap particles by forced hydrolysis of Ca(OH)2–Na4P2O7 solution

2016 ◽  
Vol 124 (6) ◽  
pp. 737-743 ◽  
Author(s):  
Kazuhiko KANDORI ◽  
Mika NAKANISHI
2015 ◽  
Vol 120 ◽  
pp. 271-278 ◽  
Author(s):  
Marcelo Müller ◽  
Juan Carlo Villalba ◽  
Filipe Quadros Mariani ◽  
Mariane Dalpasquale ◽  
Milena Zvolinski Lemos ◽  
...  

1992 ◽  
Vol 47 (1) ◽  
pp. 121-125 ◽  
Author(s):  
Sigrídur Jónsdóttir ◽  
Günter Klar

Reactions of aquacobalamine with dimethyl and diphenyl phenylphosphonite and with methyl diphenylphosphinite lead to neutral complexes in which the partially hydrolyzed an ionic ligands [PPh(OR)(O)]- (R = Me, Ph) and [PPh2(O)]- are P-bonded to the cobalt(III) ion of the cobalamine moiety. Hydrolysis of the prochiral phosphonite already coordinated to the chiral cobalamine leads to two diastereomers which are formed in different yields. This optical induction is seen in the 1H and 31P{1H} N M R spectra.


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