Thermo-acoustical parameters study in 3 binary liquid mixtures of quinoline with methanol, ethanol and 1-propanol at temperatures T=(303.15,308.15,313.15 and 318.15)K

2016 ◽  
Vol 72 (3) ◽  
Author(s):  
SK. FAKRUDDIN ◽  
Dr. Rambabu ◽  
Dr.K. Narendra ◽  
Dr.Ch. Srinivasu ◽  
P. Shakira
2009 ◽  
Vol 6 (4) ◽  
pp. 1150-1152 ◽  
Author(s):  
R. Uvarani ◽  
J. Sivapragasam

Molecular interaction studies using ultrasonic technique in the binary liquid mixtures of cyclohexanone witho-cresol andp-cresol have been carried out at 303 K. Using the measured values of ultrasonic velocity, density and viscosity, acoustical parameters and their excess values are evaluated. From the properties of these excess parameters the nature and strength of the interactions in these binary systems are discussed.


Author(s):  
G. Alamelumangai ◽  
N. Santhi

The wide spread use of 1,3,4-oxadiazoles as a scaffold in medicinal chemistry establishes this moiety as an important bioactive class of heterocycles. In the present study ultrasonic velocity (u), density (ρ) and viscosity (η) have been measured at frequency 2 MHz in the binary mixtures of 1,3,4-oxadiazole derivatives in acetone at 303.15 K using ultrasonic interferometer technique. The measured value of ultrasonic velocity, density and viscosity have been used to estimate the acoustical parameters namely adiabatic compressibility (βad), relaxation time (τ), acoustic impedance (Zi), free length (Lf), free volume (Vf) and internal pressure (πi), with a view to investigate the nature and strength of molecular interactions. The obtained result support the occurrence of molecular association through hydrogen bonding in the binary liquid mixtures.


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