Novel Stereoselective Synthesis of (Z)-α,β-Unsaturated Esters by Hydrostannylation-Stille Tandem Reaction of Alkynyl Esters with Aryl Iodides

Sulfonyl hydrazones have been identified as an excellent sulfonyl anion surrogate in the tandem reaction with aryl iodides and allenes for the synthesis of functionalized (Z)-allylic sulfones.

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A stereoselective synthesis of (Z)- and (E)-trifluoromethylated .alpha.,.beta.-unsaturated esters via intramolecular Wittig reaction

The Journal of Organic Chemistry ◽

10.1021/jo00069a014 ◽

1993 ◽

Vol 58 (17) ◽

pp. 4564-4566 ◽

Cited By ~ 37

Author(s):

Yanchang Shen ◽

Shu Gao

Keyword(s):

Wittig Reaction ◽

Stereoselective Synthesis ◽

Unsaturated Esters ◽

Intramolecular Wittig Reaction ◽

Alpha Beta

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syn-Selective Reformatsky-Type Reaction of α-Silyl-α-stannylacetic Esters with Aldehydes: Stereoselective Synthesis of (E)- and (Z)-α,β-Unsaturated Esters

Synlett ◽

10.1055/s-1991-20921 ◽

1991 ◽

Vol 1991 (12) ◽

pp. 911-912 ◽

Cited By ~ 10

Author(s):

Shuji Akai ◽

Yasunori Tsuzuki ◽

Satoshi Matsuda ◽

Shinji Kitagaki ◽

Yasuyuki Kita

Keyword(s):

Stereoselective Synthesis ◽

Unsaturated Esters ◽

Type Reaction

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ChemInform Abstract: Palladium-Catalyzed Tandem Reaction of Alkyne-Based Aryl Iodides and Salicyl N-Tosylhydrazones to Construct the Spiro[benzofuran-3,2′-chromene] Skeleton.

ChemInform ◽

10.1002/chin.201639105 ◽

2016 ◽

Vol 47 (39) ◽

Author(s):

Xue Song Shang ◽

Nian Tai Li ◽

Deng Yuan Li ◽

Pei Nian Liu

Keyword(s):

Tandem Reaction ◽

Aryl Iodides ◽

Palladium Catalyzed

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ChemInform Abstract: Stereoselective Synthesis of (2Z)-α-Bromo-α,β- Unsaturated Esters via Arsonium Ylide.

ChemInform ◽

10.1002/chin.199624090 ◽

2010 ◽

Vol 27 (24) ◽

pp. no-no

Author(s):

Z.-Z. HUANG ◽

L.-L. WU ◽

L.-S. ZHU ◽

X. HUANG

Keyword(s):

Stereoselective Synthesis ◽

Unsaturated Esters

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A convenient stereoselective synthesis of β-lactams from β-hydroxy-α-thioalkylesters prepared from Michael/aldol tandem reaction or stereoselective addition of thiols to the Baylis–Hillman adducts

Tetrahedron ◽

10.1016/j.tet.2003.10.035 ◽

2003 ◽

Vol 59 (50) ◽

pp. 9931-9938 ◽

Cited By ~ 17

Author(s):

Akio Kamimura ◽

Rie Morita ◽

Kenji Matsuura ◽

Hiromasa Mitsudera ◽

Masashi Shirai

Keyword(s):

Stereoselective Synthesis ◽

Tandem Reaction ◽

Stereoselective Addition

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Access to chiral tetrahydrofluorenes through a palladium-catalyzed enantioselective tandem intramolecular Heck/Tsuji–Trost reaction

Chemical Communications ◽

10.1039/c9cc01379b ◽

2019 ◽

Vol 55 (26) ◽

pp. 3769-3772 ◽

Cited By ~ 11

Author(s):

Ying Zhang ◽

Hong-Cheng Shen ◽

Yang-Yang Li ◽

Yong-Shuang Huang ◽

Zhi-Yong Han ◽

...

Keyword(s):

Tandem Reaction ◽

Aryl Iodides ◽

Palladium Catalyzed

A palladium-catalyzed enantioselective tandem reaction of 2,5-cyclohexadienyl-substituted aryl iodides and carbon or heteroatom nucleophiles has been successfully established by using a chiral H8-BINOL-based phosphoramidite ligand.

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