The Synthesis and Ion-Exchange Property of Li+ Memorized Spinel Al1.5Fe0.5(PO4)2

2012 ◽  
Vol 459 ◽  
pp. 151-154
Author(s):  
Jin He Jiang

Compound Al1.5Fe0.5(PO4)2, a inverse spinel-type metal compound, was prepared by a solid state reaction crystallization method. The Li+ extraction/insertion with this material were investigated by X-ray, FT-IR spectroscopy, and Kd measurement, The chemical analysis showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 8.7mmol/g for Li+. It had a memorial ion-sieve property for Li+.

2012 ◽  
Vol 512-515 ◽  
pp. 1014-1017
Author(s):  
Jin He Jiang

A inverse spinel-type metal compound [Mg2Ti0.5(PO4)2], was prepared by a solid state reaction crystallization method. The Li+extraction/insertion with this material were investigated by X-ray, FT-IR spectroscopy, and Kd measurement, The acid treated samples had an ion exchange capacity of 8.7mmol/g for Li+. It had a memorial ion-sieve property for Li+.


2012 ◽  
Vol 490-495 ◽  
pp. 3864-3867
Author(s):  
Jin He Jiang ◽  
Bin Shan

Compound Al0.75Fe1.25(PO4)2, a inverse spinel-type metal compound, was prepared by a solid state reaction crystallization method. The Li+ extraction/insertion with this material were investigated by X-ray, FT-IR spectroscopy, and Kd measurement, The chemical analysis showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 4.0mmol/g for Li+. It had a memorial ion-sieve property for Li+.


2012 ◽  
Vol 463-464 ◽  
pp. 185-188
Author(s):  
Jin He Jiang

Compound Al2.6667Ti(PO4)4, a inverse spinel-type metal compound, was prepared by a solid state reaction crystallization method. The Li+ extraction/inserti on with this material were investigated by X-ray, FT-IR spectroscopy, and Kd measurement, The chemical analysis showed that the Li+ extraction insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 8.0mmol/g for Li+. It had a memorial ion-sieve property for Li+.


2012 ◽  
Vol 485 ◽  
pp. 442-445
Author(s):  
Heng Li

The ion-exchanger Al3Ti(PO4)4.3333 of inverse spinel type was prepared by a solid state reaction crystallization method. The Li+ extraction/insertion with this material were investigated by X-ray, FT-IR spectroscopy, and Kd measurement, The chemical analysis showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 8.2mmol/g for Li+. It had a memorial ion-sieve property for Li+.


2012 ◽  
Vol 511 ◽  
pp. 105-108
Author(s):  
Jin He Jiang

Mg1.5Mn0.5Ti0.75O4 was prepared by a coprecipitation/thermal crystallization method. The extraction/insertion reaction with this material was investigation by X-ray, saturation capacity of exchange, and Kd measurement. The acid treatments of Mg1.5Mn0.5Ti0.75O4 caused Mg2+ extractions of more than 72%, while the dissolutions of Mn4+ and Ti4+ were less than 8.2%. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 10.6mmol/g for Li+.


2012 ◽  
Vol 178-181 ◽  
pp. 467-470
Author(s):  
Jin He Jiang

Compound [Li3Mn0.5Ti0.25O3] was prepared by a solid state reaction crystallization method. It was an inverse spinel-type metal compound. The extraction/insertion reaction with this material was investigated by X-ray, saturation capacity of exchange, and Kd measurement. The acid treated samples had an ion exchange capacity of 9.7mmol/g for Li+.


2012 ◽  
Vol 549 ◽  
pp. 118-121
Author(s):  
Jin He Jiang

A spinel-type metal compound [LiMn0.5Ti0.75O3], was prepared by a solid state reaction crystallization method. The Li+ extraction/insertion with this material were investigated by X-ray and Kd measurement. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 4.2mmol/g for Li+.


2012 ◽  
Vol 424-425 ◽  
pp. 789-792
Author(s):  
Heng Li

Compound [LiZnPO4], a spinel-type metal compound, was prepared by a solid state reaction crystallization method. The experimental results showed that the Li+extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 4.1 mmol/g for Li+.


2012 ◽  
Vol 457-458 ◽  
pp. 206-209
Author(s):  
Heng Li

Compound [Li1.4Zn0.8PO4], a spinel-type metal compound, was prepared by a solid state reaction crystallization method. The results showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 6.2 mmol/g for Li+.


2012 ◽  
Vol 554-556 ◽  
pp. 874-877
Author(s):  
Jin He Jiang

Compound [Li2Mn0.5Ti0.5O3], a spinel-type metal compound, was prepared by a solid state reaction crystallization method. The Li+ extraction/insertion with this material were investigated by X-ray and Kd measurement. The chemical analysis showed that the Li+ extraction/insertion be progressed mainly by an ion-exchange mechanism. The acid treated samples had an ion exchange capacity of 7.7mmol/g for Li+.


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